斜向型非均向TiO2致密层应用于染料敏化太阳能电池-中华科技大学.PDFVIP

Journal of China University of Science and Technology Vol.59-2014.04 斜向型非均向TiO 緻密層應用於染料敏化太陽能電池 2 The Application of a Slant-Type Anisotropic TiO2 Compact Layer in Dye-Sensitized Solar Cells 黃嘉輝 1 劉竹峰 2* Chia-Hui, Huang Ju-Feng, Liu 中華科技大學電子研究所碩士班研究生 1 中華科技大學電子研究所副教授 2* Department of Electronic Engineering China University of Science and Technology 摘 要 本研究提出在染料敏化太陽能電池使用斜向型非均向TiO2 緻密層結構，使緻 密層結構更為密實以減少逆反應，並可於緻密層介面形成特殊紋理提升光捕捉效 率，而使電池光電轉換效率大幅提升。非均向 TiO2 緻密層以射頻濺鍍法，藉由調 整載具角度以 20° 、60° 及 80° 、三種角度，將TiO2 薄膜沉積在ITO 導電玻璃 上，以製作染料敏化太陽能電池，另外我們亦製作傳統 0°之非均向 TiO2 緻密層 以作為比較。實驗結果顯示，將非均向TiO2 緻密層之奈米柱做傾斜後，電池轉換 效率可由傳統 0°之 1.58% ，分別對應20° 、60° 及 80°三種沈積角度，提升至 2.66% 、3.18% 、4.38% ，有非常好的改善效果，且改善程度隨沉積角度增加而提 升。 關鍵詞 : 緻密層、染料敏化太陽能電池、非均向、濺鍍、二氧化鈦 ABSTRACT We present a slant-type anisotropic TiO2 compact layer applied on dye-sensitized solar cells (DSSC). Because the back reaction is reduced owing to the denser compact layer structure and the light harvesting efficiency is enhanced owing to the special texture on the surface of the compact layer, the efficiency of the conversion of solar energy to electricity is significantly improved. The slant-type anisotropic TiO2 compact layers were grown on ITO conductive glass substrates using radio frequency sputtering and then DSSC were produced for evaluating the effect of the compact layers in DSSC. By adjusting the angle of the vehicle at 20°, 60°and 80°, the TiO2 films were deposited. 93 斜向型非均向TiO 緻密層應用於染料敏化太陽能電池 2 We also grew con