页岩油储集能力孔喉阈值探究.docVIP

SUPPORTING INFORMATION Do Shale Pore Throats Have a Threshold Diameter for Oil Storage? Caineng Zou1, Xu Jin1,2, Rukai Zhu1, Guangming Gong2, Liang Sun1, Jinxing Dai1, Depeng Meng2, Xiaoqi Wang1, Jianming Li1, Songtao Wu1, Xiaodan Liu1, Juntao Wu2 Lei Jiang2,3 1PetroChina Research Institute of Petroleum Exploration Devel-opment (RIPED), Beijing, 100083, P.R. China, 2Key Laboratory of Bio-Inspired Smart Interfacial Science, Tech-nology of Ministry of Education, School of Chemistry and Enviroment, Beihang University, Beijing, 100191, P.R. China, 3Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, Beijing, 100190, P.R. China. Correspondence and requests for materials should be addressed to X. J. (jinxu@) or J.W. (wjt@). 3D animations of the inner structure of shale and its abstracted pore channels are presented in MOVIE S1 and MOVIE S2. Characterizations of shale rocks were conducted using X-RADIATM Nano CT and FEITM FIB-SEM. Scheme S1. Characterization flow of 3D pore structure of shale rocks using Xradia UltraXRM-L200 Nano-CT and Helios 640 FIB-SEM: 1. Slice image acquisition; 2. Phase identification and segmentation; 3. 3D reconstruction and visualization; 4. Digital core analysis and data processing. Nano-scale X-ray Microscope (Xradia UltraXRM-L200, USA) provides insight into the microscopic structures and processes with a resolution as fine as 50 nm, which were not previously accessible with conventional lab-based X-ray technology. Producing 8 keV X-rays with excellent penetration and contrast for a wide range of samples, NanoCT enables observation of structures and materials in their natural state. The integrated phase contrast mode with the Zernike method improves the visibility of grain boundaries and material interfaces when the absorption contrast is low, enabling visibility of nano-structure. FIB-SEM (FEI Helios Nanolab 650, USA) provides a high resolution o