研究基于环糊精的分子组装.pptVIP

二、基于环糊精的分子组装 基于天然环糊精的分子组装 基于单修饰环糊精的分子组装 基于桥联双环糊精的分子组装 -环糊精与2,2´-联吡啶形成头对头通道结构及其联吡啶骨架 -环糊精与2,2’-联吡啶和4,4’-联吡啶的键合能力及其组装行为 -环糊精与4,4´-联吡啶形成头对头通道结构及其联吡啶骨架 (a) (b) (a) -环糊精与2,2´-联吡啶以及与 (b) 4,4´-联吡啶在水溶 液中的可能结构. 反 应 KS G° H° TS° 2-DPD + -CD 71±12 10.5±0.5 6.4±0.7 4.1±1.2 4-DPD + -CD 164±9 12.6±0.2 5.7±0.3 6.9±0.5 J. Org. Chem. 2004, 69(10), 3383-3390. 在25 C的水溶液中-环糊精与联吡啶包结络合作用的稳定常数(KS)、自由能变化(G) 、焓变(H)和熵变(TS). 通过环糊精、有机分子和金属离子构筑多聚轮烷示意图 通过-环糊精与4,4’-联吡啶的包结络合物与二价镍离子的配位作用构筑多聚轮烷 Angew. Chem. Int. Edit. 2003, 42(28), 3260-3263 联吡啶、环糊精包合物1以及聚轮烷2的核磁氢谱 聚轮烷2的STM 图象 聚轮烷2的TEM 图象 环糊精/联吡啶包合物(a)1和(b)3在D2O中的ROESY光谱，混合时间200 ms. 假聚轮烷4的TEM图像， 假聚轮烷4的高分辨TEM图像 (c) 假聚轮烷6的TEM图像， (d) 假聚轮烷6的高分辨TEM图像 a b c d (a) 假聚轮烷6的STM图像，(b) a图的局部放大图，(c) b图的3D图像 (d) b图和c图的线装轮廓图 Chem. Mater., 2006, 18(18), 4423-4429 . 以Co2+ 和Zn2+ 配位中心和环糊精/联吡啶包结配合物构筑的纳米构建物 The TEM images of polypseudorotaxane aggregation 2, showing the square nanostructures. The TEM images of polypseudorotaxane aggregation 3, showing the rod nanotructures. The TEM images of polypseudorotaxane aggregation 4, showing the square nanotructures. The TEM images of polypseudorotaxane aggregation 5, showing the rod nanotructures. The TEM images of polypseudorotaxane aggregation 6, showing the rod nanotructures. The TEM images of polypseudorotaxane aggregation 7, showing the square nanostructures. (a) The molecular modeling structure of a short oligomer of the polypseudorotaxanes. (b) Possible assembly mode for nanosquare superstructure of polypseudorotaxanes. (c) Possible assembly mode for nanorod superstructure of polypseudorotaxanes. The colors of polypseudorotaxanes 2 (blue), 3 (pink), and 4 (pink). Synthetic route of AuNP aggregation 2. Org. Lett., 2006, 8(7), 1267-1270. 以金纳米离子为中心的多聚[2]轮烷 Synthesis of rotaxane-capped gold nanoparticle 4. (a-c) Typical TEM images of 4. The size labels are 20 nm for (a) and (b), 10 nm for (c). (d) size-dependent histogram of