ReactionsofAlkenes教学幻灯片讲义.pptVIP

Because they proceed by way of polar ion-pair intermediates, chlorine and bromine addition reactions are faster in polar solvents than in non-polar solvents, such as hexane or carbon tetrachloride. However, in order to prevent solvent nucleophiles from competing with the halide anion, these non-polar solvents are often selected for these reactions. In water or alcohol solution the nucleophilic solvent may open the bromonium ion intermediate to give an α-halo-alcohol or ether, together with the expected vic-dihalide. Such reactions are sensitive to pH and other fac