蛤蜊壳羟基磷灰石的制备及对Pb2的吸附性能.PDFVIP

※基础研究 食品科学 2013, Vol.34, No.13 39 蛤蜊壳羟基磷灰石的制备及对Pb2+ 的吸附性能 金 科，李振兴，吴玟静，林 洪* ( 中国海洋大学食品安全实验室，山东 青岛 266003) 摘  要：目的：探讨蛤蜊壳羟基磷灰石(HA)对铅的吸附性能。方法：以废弃蛤蜊壳为原料，在常温下运用沉淀法 X (XRD) (SEM) (FTIR) 制备羟基磷灰石，通过 射线衍射 、扫描电子显微镜 及红外光谱 表征产物的晶相组成、形貌及化 学组成等，并采用模拟Pb2+溶液，考察时间、pH值、温度及初始Pb2+质量浓度对吸附效果的影响，从动力学和热力 学角度探讨其吸附规律。结果：在pH3.0 时，吸附效果最好，酸性环境有利于吸附，随着pH值的增大吸附容量逐渐 降低；反应30min时基本达到吸附平衡；吸附容量随着初始溶液Pb2+质量浓度的增大而增大，高温有利于吸附反应 的进行。结论：以蛤蜊壳为原料制备的羟基磷灰石对Pb2+有良好吸附效果，其吸附规律可以用Langmuir吸附模型描 述，符合拟二级动力学模型，是一个自发的吸热反应。 关键词：蛤蜊壳；羟基磷灰石；Pb2+ ；吸附 Preparation of Hydroxyapatite from Clam Shell and Its Adsorption Capacity for Pb2+ JIN Ke ，LI Zhen-xing ，WU Wen-jing ，LIN Hong* (Food Safety Laboratory, Ocean University of China, Qingdao 266003, China) Abstract ：Purpose: To investigate the adsorption capacity of hydroxyapatite prepared from clam shell for Pb2+ . Methods: Hydroxyapatite was prepared from clam shell by precipitation method under room temperature, and its crystal phase composition, morphology and chemical composition were characterized by employing X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR). Adsorption of Pb2+ solution models by the hydroxyapatite adsorbent was investigated with respect to various parameters such as adsorption time, pH, temperature and initial Pb2+ concentration and the adsorption kinetics and thermodynamics were also explored. Results: The best adsorption capacity was found at pH 3.0. An acidic environment favored Pb2+ adsorption, and the adsorption capacity of hydroxyapatite was gradually reduced with increasing pH. The adsorptio