RhFe3O4纳米复合粒子的合成和性质研究.DOCVIP

RhFe304纳米复合粒子的合成和性质研 究 马晨光李春艳湛世霞方宁刘红玲 河南省多酸化学重点实验室河南大学化学化工学院 分子与晶体工程研究所 采用纳米微乳液法，以乙酰丙酮铁(Fe (acac) 3) ＞醋酸铑([Rh (OOCCH3) 2]2) 为前驱体，1, 2-十六烷二醇为还原剂，正辛醚为溶剂，三嵌段共聚物聚氧乙烯- 聚氧丙烯-聚氧乙烯(PEO-PPO-PEO)为表面活性剂成功合成了双相可分散的 RhFe304纳米复合粒子.傅立叶变换红外光谱仪(H-IR)分析表明该纳米复合 粒子表而存在两亲性PEO-PPO-PEO分子，X-射线衍射仪(XRD)分析表明纳米复 合物中含有Rh和Fe30b透射电子显微镜(TEM)测试表明该纳米复合粒子基本 呈球形或多面体形、粒径分布窄、结晶度高，振动样品磁强计(VSM)测试表明 该纳米复合粒子在室温下显示软铁磁性.RhFeA纳米复合粒子在水和正己烷中的 分散-聚集过程，表明其具有良好的双相分散性和磁操控性.兼具良好催化活性 和磁性的RhFe30,纳米复合粒子有望在催化、生物医药中有潜在的应用. 关键词： 微乳液法;RhFe3O4纳米复合粒丫?:双相可分散;磁学性质; 马晨光(1990-)，男，生.主要从事纳米多酸材料的研究. 刘红玲，posite Nanoparticles MA Chenguang LI Chunyan ZHAN Shixia FANG Ning LIU Hongling Key Laboratory of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering， College of Chemistry and Chemical Engineering, Henan University; Abstract： Bi-phase dispersible RhFe304 composite nanoparticles were successfully synthesized by nanocmulsion method with Fc (acac) 3 and rhodium diacctatc [Rh (OOCCH3) 2]2 as precursors, 1，2-hexadecanediol as reducing agent, n-octyl ether as solvent and triblock copolymer poly (ethylene glycol) -block-poly (propylene glycol) -blockpoly (ethylene glycol) (PEO-PPO-PEO) as the surfactant. Fourier transform infrared spectroscopy (FT-TR) analysis shows that there arc amphiphilic PEO-PPO-PEO molecules on the surface of the composite nanoparticles. X-ray diffraction (XRD) analysis shows that the composite nanoparticles contain Rh and Fe30,. Transmission electron microscopy (TEM) test shows that the composite nanoparticles possessing narrow particle size distribution and high crystallinity are spherical or polyhedral. Vibrating sample magnetometer (VSM) measurement shows that the composite nanoparticles manifest soft ferromagnetic at room temperature. The dispersion-aggregation process of RhFeA composite nanoparticles in water and n-hexane indicates that they behave good bi-phase dispersibility and magnetic handling. RhFe3Oj composite nanoparticles with good catalytic activity and magnetic