毕业设计（论文）-金属钴的表面修饰及其催化析氢的研究精选.docxVIP

金属钴的表面修饰及其催化析氢的研究目 录摘要ⅠAbstractⅡ引 言1第1章 文献综述21.1 钴的性质及应用21.1.1钴的性质21.1.2钴的应用21.2 钴的表面修饰及其催化析氢的研究21.2.1研究的目的及意义21.2.2国内外研究现状31.2.3钴的表面硫化及其机理31.2.4金属催化析氢机理的研究31.3修饰电极的电化学性能表征方法4第2章 实验部分52.1仪器与试剂52.2 实验方法及步骤52.2.1 钴片的预处理52.2.2设置空白对照组52.2.3钴片的表面硫化52.2.4硫化钴电极催化析氢活性的测定6第3章 结果与讨论83.1水热温度对析氢反应活性的影响83.2修饰剂硫脲浓度对析氢反应活性的影响143.3体系温度对析氢反应活性的影响233.4不同电解液对析氢反应活性的影响313.4.1不同酸碱度电解液的影响313.4.2不同浓度电解液的影响32结 论34致 谢35参考文献36金属钴的表面修饰及其催化析氢的研究摘要:过渡金属硫化物如硫化锆、硫化钴等材料作为电解析氢反应的电极是研究的热点。采用水热反应法对金属钴片进行表面修饰，选取硫脲作为修饰剂使钴片表面硫化，然后通过稳态阴极极化曲线法测出表面修饰的硫化钴的电化学性质，根据电极电势和电流密度的大小来分析其催化析氢性能的优劣。电流密度值越大，析氢反应速率越快，催化活性越好。实验研究结果表明：在一般情况下，可选取硫化温度为180 oC，硫脲浓度为0.1 mol L-1作为较优的表面修饰条件；当配制的硫脲浓度较小时表面修饰效果较好，其催化析氢性能越强；随着电解液体系温度的升高，催化析氢性能增强；随着电解液浓度的增大，催化析氢性能增强。本文还考察了硫化钴片在酸碱盐不同性质的电解液中的催化析氢性能，主要对象为盐溶液。关键词：钴片 硫脲 阴极极化曲线 催化析氢Study on the Surface Modification of Cobalt and its Catalytic Hydrogen EvolutionAbstract: Transition metal sulfides, such as zirconium sulfide and cobalt sulfide, are the hot spots in the study of hydrogen evolution reaction. The surface of cobalt was modified by hydrothermal method, and the surface of cobalt was modified by thiourea as the modifier, and then the catalytic hydrogen evolution performance of surface modified cobalt sulfide was measured by the steady state polarization curve method, according to the electrode potential and current density, the catalytic hydrogen evolution performance is analyzed. The higher the current density, the faster the reaction rate of hydrogen evolution, the better the catalytic activity. The experimental results show that: under normal circumstances, we can choose the curing temperature of 180 oC, thiourea concentration of 0.1 mol L-1 as the best surface modification conditions; When the thiourea concentration is small, the surface modification effect is better, and the catalytic hydrogen evolution performance is stronger; With the increase of the temperature of the electrolyte system, the catalytic hydrogen evolution performance is enhanced; With the increase of electrol