TiO2 实验室制备.pdfVIP

ARTICLE IN PRESS Journal of Solid State Chemistry 182 (2009) 749–756 Contents lists available at ScienceDirect Journal of Solid State Chemistry journal homepage: /locate/jssc Morphological and phase evolution of TiO2 nanocrystals prepared from peroxotitanate complex aqueous solution: Influence of acetic acid Jeong Ah Chang, Muga Vithal, In Chan Baek, Sang Il Seok KRICT-EPFL Global Research Laboratory, Advanced Materials Division, Korea Research Institute of Chemical Technology, 19 Sinseongno, Yuseong, Daejeon 305-600, Republic of Korea a r t i c l e i n f o a b s t r a c t Article history: Nanosized anatase and rutile TiO2 having different shape, phase and size have been prepared from Received 15 October 2008 aqueous solutions of peroxo titanium complex starting from titanium(IV) isopropoxide (TTIP), acetic Received in revised form acid and hydrogen peroxide (H O ) in water/isopropanol media by a facile sol–gel process. The TiO 2 2 2 20 December 2008 nanocrystals are characterized by powder X-ray diffraction (XRD), Raman spectroscopy, FT-IR Accepted 30 December 2008 spectroscopy, TEM, high resolution transmission electron microscopy (HRTEM) and selected area Available online 6 January