Nb掺杂对双钙钛矿化合物居里温度的影响.pdfVIP

28 4 ( ) Vol. 28 No. 4 2004 7 Jour nal of Hebei Normal Univer it y ( N atural Science Edition) Jul. 2004 Nb 掺杂对双钙钛矿化合物居里温度的影响 1 1 1 2 3 赵 旭, 栗 萍 , 唐贵德, 张变芳 , 禹日程 ( 1. , 050016; 2. , 050043; 3. , 100080) : Sr FeMo Nb O Mo Nb , x [ 0. 40 2 1- x x 6 Nb Mo, , B , Sr FeMoO , Nb . , Nb , Fe3+ 2 6 , . : ; Nb ; : O 482. 54 : A : 1000-5854( 2004) 04-0358-03 1998 , Kobaya hi[ 1] A BBcO ( GMR) Sr FeM oO , 2 6 2 6 4 10~ 450 K, ( T MR) , 1. 5 T 6% ( M R = [ Q( H ) - Q( 0)] ) / Q( 0) ) . , , . Sr FeM oO - , , 0. 03 8 #cm , 2 6 [ 2] , . , , , . , , , , [ 3, 4] . [ 1] 3+ 5+ Sr FeMoO , Fe ( s = 5/ 2) Mo ( s = 1/ 2) . Sr FeMoO 2 6 2 6 3+ 5 5+ 1 , Fe ( 3 d ) s = 5/ 2 , Mo 4 d 5 1 . , T c , s = 5/ 2 3 d s = 1/ 2 4 d ; , Sr FeNbO , 2 6 3+ 5+ 0 [ 5] ( T N) 25 K, Fe ( s = 5/ 2) , Nb ( 4 d ) . B , Nb Mo , Nb5+ . , Sr FeMo Nb O , 2 1- x x 6 Nb5+ , . 1