ZnO压敏电阻的化学蜕变.pdf

DOI:10.14106/j.cnki.1001-2028.2002.04.005 第4 期 电 子 元 件 与 材 料 Vol.21 No.4 2002 年4 月 ELECTRONIC COMPONENTS MATERIALS Apr. 2002 研究与试制 R D ZnO 压敏电阻的化学蜕变 1 2 2 李标荣 ，陈万平 ，陈王丽华 (1.广州新日电子有限公司，广东 广州 510335；2.香港理工大学应用物理系，香港 九龙) 摘要:ZnO 压敏电阻在0.05 mol/L NaOH 的电解液中作直流电解处理后，出现化学蜕变，漏电流增加、非线性特 性减弱，经热处理后其压敏特性又可恢复。它与通常的电学蜕变不同，经论证认为，这种蜕变是属于氢原子在瓷体晶 粒边界附近中的还原作用所致。文中还讨论了其可能的蜕变机理。 关键词:压敏电阻；化学蜕变；蜕变机理；氢还原 中图分类号: TN304.93；TM534.1 文献标识码:A 文章编号:1001-2028 （2002）04-0012-03 Chemical Degradation in ZnO-based Varistors 1 2 2 LI Biao-rong , CHEN Wan-ping , CHENWANG Li-hua (1. Guangzhou Sunrise Electronic Co., Ltd., Guangzhou Guangdong 510335; 2. Dept. of Appl. Physics, Hong Kong Polytechnic University, Kowloon Hong Kong) Abstract: ZnO varistors being placed in a 0.05 mol/L NaOH solution to be DC electrolyzed can lead to increased leakage current, weakened nonlinear characteristic and other degradation phenomena. After heat treatment at 650 ℃, its characteristic can be recovered. The mechanism is different from conventional electrical degradation. It is proved that it is the hydrogen atoms produce reduction reaction round the grain boundaries of the ceramics. The possible degradation mechanis m is also discussed . Key words : varistors; chemical degradation; degradation mechanism; reduction with hydrogen ZnO 压敏电阻的蜕变（degradation）有时也被习 惯地称为老化（ageing