[高等教育]chapter 7 Two-component phase diagram and the alloy solidification.ppt

The equilibrium crystallization process of solid solution alloy Temperature / oC Time / min b). The equilibrium solidification of solid  solution－B The solidification of solid solution has two prominent characteristics compared to the solidification of pure metals: (1). Solid-phase composition out of the solid solution when the solid solution alloy curdles and crystallizes. The crystallization composition is the same with chemical composition of parent phase for cure metals. (2). The solidification of solid solution needs a certain temperature. A number of crystal solid phase is received during this temperature rang. b). The equilibrium solidification of  solid solution －C There are three processes of the equilibrium solidification of solid solution at certain temperature. [1] Diffusion process in the liquid phase. [2] The continued growing of the solid phase. [3] Diffusion process in the solid phase. Conditions of equilibrium solidification are realized only for extremely slow cooling rates. The reason for this is that with changes in temperature, there must be readjustments in the compositions of the liquid and solid phases in accordance with the phase diagram. These readjustments are accomplished by diffusional processes—that is, diffusion in both solid and liquid phases and also across the solid–liquid interface. c). Non-equilibrium solidification of solid solution-A The nonequilibrium solidification phenomenon is that the solidus line on the phase diagram has been shifted to higher Ni contents and is represented by the dashed line in Fig. 7.15. Non-equilibrium microstructure is obtained in the process of nonequilibrium solidification. Figure 7.15 Schematic representation of the development of microstructure during the nonequilibrium solidification of a 35 wt% Ni–65 wt% Cu alloy. c). Non-equilibrium solidification of solid  solution-B The following conclusion is obtained t