介孔金属硅材料外文文献.pdfVIP

Microporous and Mesoporous Materials 257 (2018) 175e184 Contents lists available at ScienceDirect Microporous and Mesoporous Materials journal homepage: /l ocate/micromeso Mesoporous metal - silica materials: Synthesis, catalytic and thermal properties Khachatur V. Manukyan a, *, Armenuhi V. Yeghishyan b, Christopher E. Shuck b, Dmitry O. Moskovskikh c, Sergei Rouvimov d, Eduardo E. Wolf b, Alexander S. Mukasyan b a Nuclear Science Laboratory, Department of Physics, University of Notre Dame, Notre Dame, IN 46556, USA b Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN 46556, USA c National University of Science and Technology, ‘‘MISIS ’’, Moscow 119049, Russia d Department of Electrical Engineering, University of Notre Dame, Notre Dame, IN 46556, USA a r t i c l e i n f o a b s t r a c t Article history: Here, we report a simple and scalable synthesis strategy of metal (Ni or Cu) nanoparticles uniformly Received 5 May 2017 distributed inside a mesoporous silica matrix. This method involves incorporation of metal nitrates and Received in revised form citric acid in a stable silica gel through controlled hydrolysis of tetraethyl orthosilicate. Combustion of 13 August 2017 dried gels with ammonium nitrate in an inert gas atmosphere enables preparation of highly porous Ni/ Accepted 23 August 2017 SiO2 and Cu/SiO2 nanomaterials with tunable metal content (~5e30 wt.%). This approach also allows for Available online 26 August 2017