网版印刷碳电极的品质表现.PDF

绂瓬绉戞妧 4.1 缍茬増鍗板埛纰抽浕妤 4.1 缍茬増鍗板埛纰抽浕妤 缍茬増鍗板埛纰抽浕妤垫槸20涓栫磤寰堥噸瑕佺殑涓€闋呯櫦鏄庣敘鍝 锛屽湪闆诲垎鏋愬寲瀛搁牁鍩熶腑 锛屾闋呯敘鍝 鏀硅畩浜嗗偝绲辨媼鍏夐浕妤电殑瀵﹂浣跨敤鏂瑰紡 锛屽緸闇€瑕佹媼鍏夊埌鍙媼妫勫紡闆绘サ澧為€蹭簡鐮旂┒閫熷害 鑸囪兘閲 銆傜恫鐗堝嵃鍒锋妧琛撴槸鍒╃敤涓€鍏锋湁绱板井瀛旀礊鐨勭恫鐗 锛屽皣娌瑰ⅷ鎿犲閫忛亷缍茬増鑰屽嵃瑁 鍦ㄧ洰妯欒級楂斾笂 锛屽洜姝ゅ彲瑷▓鍗板埛鐗瑰畾褰㈢媭鑸囧ぇ灏 锛屼竴鑸嵃瑁界殑娌瑰ⅷ绶氬浠嬫柤100 渭m 鑸囨暩鍊嬫绫充箣闁 锛屽帤搴﹀墖鏈€钖勭磩鐐?0 渭m 銆傛劅娓櫒闋樺煙涓唬鐐烘噳鐢ㄧ殑鐢㈠搧鑾潪琛€绯栨劅 娓櫒涓嶅彲 锛屽叾渚涙噳钁楀叏涓栫晫鏈€澶х殑閱檪鍣ㄦ潗甯傚牬浠ュ崝鍔╃硸灏跨梾鎮ｅ緱浠ョ董鎸佸仴搴风殑韬 楂旂媭鎱 銆傞櫎姝や箣澶 锛岀恫鐗堝嵃鍒风⒊闆绘サ涔熻寤ｆ硾鎳夌敤闁嬬櫦鍦ㄧ敓鐗╂劅娓櫒 銆佺挵澧冩娓 銆 椋熷搧瀹夊叏 銆佸厤鐤垎鏋 銆侀啱钘ユ娓強鍏夐浕鐢㈠搧绛夐牁鍩熺暥涓 銆 2 FOR INTERNAL USE ONLY 4.1.1 绂瓬绉戞妧鐢熺敘瑁介€犵恫鐗堝嵃鍒风⒊闆绘サ 绂瓬绉戞妧鍙緷鎿氬鎴堕渶姹傚瑁藉寲瑷▓鐢熺敘澶氭ǎ褰㈠紡 銆佸ぇ灏 銆佹潗璩殑缍茬増鍗板埛闆绘サ 锛 涓︿笖鍏锋湁鑹ソ鐨勫搧璩彲璁撶爺绌朵汉鍝″畨蹇冧笖灏堝績鏂肩爺绌 闁嬬櫦 锛屽鍦栨墍绀 锛岀⒊鍠浕妤 銆 纰充笁闆绘サ 銆佺敋鑷崇⒊澶氶浕妤 銆佹柟褰㈤浕妤 銆佹墖褰㈤浕妤电殕鐢辩Κ璀滅鎶€灏堢偤瀹㈡埗閲忚韩瑷傝＝鐨 缍茬増鍗板埛纰抽浕妤 锛岄浕妤佃〃闈㈢鐨勬帶鍒 銆佷笁闆绘サ闁撶殑璺濋洟瑷畾 銆佸闆绘サ鐨勭┖闁撴瘮渚嬭ō 瑷堢殕鏄噸瑕佺殑鍝佽唱鍥犵礌 锛屽洜姝ょΚ璀滅鎶€鐨勫骞磋＝閫犺垏瑷▓缍撻鍙彁渚涗娇鐢ㄨ€呭畬缇庡搧 璩殑缍茬増鍗板埛纰抽浕妤 銆 纰虫补澧ㄦ槸缍茬増鍗板埛纰抽浕妤垫壆婕旇憲鏍稿績鐨勮鑹 锛屽叾涓⒊绮掔殑澶у皬鑸囧瀷鎱 銆佽仛鍚堟帴钁楀姂 鐨勬垚鍒嗚垏姣斾緥鍙婂叾浠栭噸瑕佹坊鍔犲姂鎺ュ奖闊垮嵃鍒峰搧璩殑濂藉 锛屽敮鏈夌簿婧栧湴鎺у埗姣斾緥鑸囧毚 (1) 鏍肩殑瑁介€犺姹傛墠鑳介€犲氨鍑哄畬缇庣殑鐢㈠搧 銆 (1)Joseph Wang, Baomin Tian,a Valeberes. Nascimento and Lucio Angnes, Electrochimica Acta, Vol. 43, No. 23, pp. 3459-3465, 1998 3 FOR INTERNAL USE ONLY 4.1.2 缍茬増鍗板埛纰抽浕妤电殑鍝佽唱琛ㄧ従 濡備綍鐭ラ亾涓€鏀恫鐗堝嵃鍒风⒊闆绘サ鏄惁鍝佽唱鑹ソ鏄娇鐢ㄨ€呭繀闋堢煡閬撲簡瑙ｇ殑 锛屽叾涓垜鍊戝繀 闋堣€冩叜鍒版椿鎬у伐浣滈浕妤甸潰绌?electroactive surface area of working electrode) 銆佺暟 璩 閫 鐜 甯 鏁 (heterogeneous rate constant) 鍙婃哀 鍖 閭 鍘 闆 浣 宸 (peak to peak separation of redox system)绛夐噸瑕佹€ф寚妯 銆傜恫鐗堝嵃鍒风⒊涓夐浕妤靛彇浠ｄ簡鍌崇当涓夐浕妤电郴 绲 锛屽ぇ澶ф笡灏戜簡婧舵恫浣跨敤閲忚垏闆绘サ闁撹窛鎺у埗鍟忛 锛屽儏闋堝埄鐢ㄧ恫鍗版妧琛撳嵆鍙＝閫犲嚭闆 妤甸潰绌嶄竴鑷寸殑涓夐浕妤电郴绲 锛屽彲绮炬簴鎺у埗宸ヤ綔闆绘サ鑸囧弮鑰冮浕妤甸枔鐨勮窛闆 銆佽紨鍔╅浕妤甸潰 绌嶆帶鍒 锛屽畬鏁村憟鐝句竴榛冮噾姣斾緥 銆 D WE-RE A drop of analyte