辛二醇对铝酸钠溶液种分过程的影响-中国有色金属学报.PDFVIP

第 17 卷第 11 期 中国有色金属学报 2007 年 11 月 Vol.17 No.11 The Chinese Journal of Nonferrous Metals Nov. 2007 文章编号：1004-0609(2007)11-1893-05 1,2-辛二醇对铝酸钠溶液种分过程的影响 尹周澜，张艾民，陈启元，敬叶灵，曾纪术 ( 中南大学 化学化工学院，长沙 410083) 摘 要：研究 1,2-辛二醇对铝酸钠溶液种分过程的影响。结果表明，1,2-辛二醇通过吸附在晶种表面对铝酸钠溶 液种分过程产生抑制作用。1,2-辛二醇的添加浓度、实验温度以及苛碱浓度等因素对 1,2-辛二醇改善铝酸钠溶液 种分效果具有显著影响。添加浓度小于 1.25 mmol/L 时，1,2-辛二醇对铝酸钠溶液的抑制程度很小；添加浓度超过 1.5 mmol/L，抑制作用非常明显。温度越低，苛碱浓度越大，1,2-辛二醇对铝酸钠溶液分解抑制作用越大。 关键词：铝酸钠溶液；1,2-辛二醇；分解率 中图分类号：TF 111.34 文献标识码：A Effect of 1,2-Octanediol on seeded precipitation of sodium aluminate solution YIN Zhou-lan, ZHANG Ai-min, CHEN Qi-yuan, JING Ye-ling, ZENG Ji-shu (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: Effect of non-ionic surfactant 1,2-Octanediol on the seeded precipitation of sodium aluminate solution has been investigated. The experimental results show that 1,2-Octanediol has inhibitory effect on gibbsite precipitation by adsorption on the surface of seeds. The concentration of 1,2-Octanediol, experimental temperature and caustic concentration of liquor can obviously affect the seeded precipitation of sodium aluminate solution. When the concentration of 1,2-Octanediol in the solution is less than 1.25 mmol/L, the inhibitory effect on gibbsite precipitation is limited. However, when the concentration of 1,2-Octanediol in the solution is higher than 1.5 mmol/L, the inhibitory effect is large. Lower temperature and higher caustic concentration of liquor will greatly increase the inhibitory effect.