搅拌设计参数对投加沸石粉的高浓度污泥悬浮状态及其.doc

拟再审修改稿 稿件编号：200708043 投加沸石粉活性污泥搅拌参数优化及其对离子交换速率的影响研究 安莹 吴志超 杨爽 （同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室，上海 200092） 摘 要 本文在0.3m×0.3m×0.36m方形搅拌槽中初步探讨了不同的搅拌器类型、安装高度以及曝气强度对投加了沸石粉的高浓度活性污泥悬浮状态的影响，并根据固液悬浮理论确定了最佳的搅拌参数。同时，进行了不同搅拌速率下沸石对污水中氨氮的离子交换动力学研究。结果表明在无曝气的情况下，选用三叶推进式搅拌器，搅拌器离底高度为1/3搅拌器直径时所需要的临界搅拌速率最低。曝气有助于反应池中污泥的悬浮，对于30g/L的污泥，当曝气强度由10m3/(m2·h)增大一倍时，临界搅拌速率降低了50%。搅拌速率为120r/min时，沸石对污水中氨氮的离子交换速率受膜扩散过程控制，当其增大为180r/min时，其控制步骤为粒内扩散，沸石粉活性污泥达到完全均匀悬浮的临界搅拌速率不足以满足传质的要求，需增大一定程度。 关键词 沸石粉活性污泥 搅拌参数 临界搅拌速率 离子交换 中图分类号 X703.1 文献标识码 A 文章编号 Optimizing of stirring factors on the activated sludge that adding zeolite and the effect on the velocity of ion exchange An Ying Wu Zhichao Yang Shuang （State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092） Abstract It was studied the effects of different types of agitator, the fixing height and the intensity of aeration on the sludge of high concentration that adding zeolite in a square stirred tank (0.3m×0.3m×0.36m) in order to the ascertain the optimum stirring factors. And according to the correlative theory, the optimum factors of stirring was ascertained .Meanwhile, the kinetics of the ammonium removal on the zeolite under different stirring speed was studied in this paper. It demonstrated that without aeration the best type of agitator is three-blade impeller and the height is 1/3 diameter of impeller. Aeration can improve the suspension of sludge. Taking the activated sludge with concentration of 30g/L for an example, the critical rotating speed was reduced 50% when the aeration intensity increased by one times. The experiments also showed that the velocity of ion exchange under 120r/min was controlled by film diffusion, which was changed into intraparticle diffusion controlling when the stirring speed was enlarged to 180r/min. The critical rotating speed should increase in order to meet the activated sludge with zeolite a