28 Alkylation by Asymmetric Phase-Transfer Catalysis：28烷基化反应中的不对称相转移催化.ppt

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28 Alkylation by Asymmetric Phase-Transfer Catalysis：28烷基化反应中的不对称相转移催化.ppt

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Alkylation by Asymmetric Phase-TransferCatalysis 张文全 Design of Chiral Phase Transfer Catalysts for Practical Amino Acid Synthesis Design of Chiral Organocatalysts for Practical Asymmetric Synthesis Bronsted Acid Catalysts Development of Bidentate Lewis Acid Chemistry and Application to Selective Organic Synthesis conclusion design new powerful PTC catalyst which contain C2-Symmetry which is different from the cinchona skeleton expand the application of the PTC in varieties of chemcal reaction * Keiji Maruoka, Professor Keiji Maruoka was born in 1953 in Mie, Japan. He graduated from Kyoto University (1976) and received his Ph.D. (1980) from University of Hawaii(Thesis Director: Prof. H. Yamamoto). He became an assistant professor of Nagoya University (1980) and was promoted to a lecturer (1985) and an associate professor (1990) there. He moved to Hokkaido University as a full professor (1995-2001), and he currently is a professor of chemistry in Kyoto University since 2000. (2007/2008). He is a board member of Chem. Commun. and is a member of the international advisory editorial board of Org. Biomol. Chem. And Chem. Asian J. His current research interests include bidentate Lewis acids in organic synthesis and practical asymmetric synthesis with chiral C2-symmetric phase-transfer catalysts and chiral bifunctional organocatalysts.. Alkylation Pioneering work O’Donnell J. Am. Chem. Soc. 1989, 111, 2353. Corey, E. J J. Am. Chem. Soc. 1997, 119, 12414. Lygo, B. Tetrahedron Lett. 1997, 38, 8595. almost all of the elaborated chiral phase-transfer catalysts reported so far have been restricted to cinchona alkaloid derivatives, which unfortunately constitutes a major difficulty in rationally designing and fine-tuning catalysts to attain sufficient reactivity and selectivity for various chemical transformations under phase-transfer catalyzed conditions Design new PTC catalyst which contain C2-Symmetry J. Am. Chem. Soc. 1999, 121, 6519. SYNLETT 2003, 12, 1931 Angew.