分子模型_PPT模版.pptVIP

Ionic liquids immobilized in alfa-Al2O3 and the test of membrane conductivity Huang yan 2009.11 Contents Experimental Conclusion Future plan Experimental [emim]PF6 (mp:58oC) 1-ethyl-3-methylimidazolium hexafluorophosphates The progress of sintering the alfa-alumina membrane Ionic liquid: Alfa-alumina: Pore size distribution of α-Al2O3 disk sintered at high temperature (A—Small α-Al2O3 particles,B—Large α-Al2O3 particles) 米万良，分多孔陶瓷负载碳纳米管膜的制备及其气体渗透性能：[天津大学博士学位论文]，天津；天津大学 58nm, ?porosity 21% 140-150nm, porosity 27% Surface of the alfa-alumina membrane support Surface of the membrane impregnated with IL. After grinding. Ionic liquid Material Density/g*cm-3 [emim]PF6 1.48 Alfa-Al2O3 2.4 Volume(Al2O3)/cm3 Volume(ionic liquid impregnated)/cm3 Volume(ionic liquid/Volume(Al2O3) 0.82 0.29 0.35 0.82 0.28 0.34 0.83 0.31 0.37 0.83 0.25 0.30 Tempreture/oC 60 110 140 170 200 230 Conductivity/mS*cm-1 0 3.3 6.2 8.9 13.5 18.6 Conductivity/mS*cm-1 0 9.4 17.7 25.4 38.6 53.1 Conductivity *Conductivity of [emim]PF6 at ambient tempreture is 5mS*cm-1 邓友全，离子液体性质、制备与应用，北京：中国石化出版社，2006 Gas permeation results Temperature/oC Room temperature 100 Rate of Gas flow/mol*cm-2s-1atm 2.37*10-9 2.37*10-9 Conclusion The alfa-Al2O3 membrane support can be completely filled with ionic liquid , forming a dense membrane. The conductivity of the dual-phase membrane is acceptable and increases with temperature. H2(1) H2(2) H+ EMF e- e- Cathode: Anode: Catalyst layer Future plan H2(1) H2(2) H+ e- e- Cathode: Anode: Catalyst layer Future plan H2 Dry N2 vN2:flow rate of N2 x:volume proportion of H2 in N2 T:temprature when testing S:eletrode area I:current F:faraday constant S:electrode area Aprotic ionic liquid, white solid at room temperature, Tm: 58oC Tm: 94.3oC Td: 435.2oC * Jean-Philippe Belieres, C. Austen Angell, J. Phys. Chem. B, 2007, 111, 4926-4937 Tamar L,Greaves, Chem.Rev., 2008,108, 206-237 Tm: 91oC Td: 260.2oC Thank you for your attention!