Simulation of complex fluids the point of view of the physicist复杂流体的物理学家的角度模拟.pptVIP

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Simulation of complex fluids the point of view of the physicist复杂流体的物理学家的角度模拟.ppt

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Simulation of complex fluids : a point of view of a physicist Simulation are well working for polymer But for pastes … What are pastes ? Model for yield stress fluids : from microscopy to constitutive equations Yield stress and aging Pastes Particles in an incompressible solvant No inertia Thermal motion - or not Interactions ( attractive, repulsive) Inertia Typical Particles interactions Pastes simple classification Rheology of pastes : problems Ceramic pastes : some problems Rheology of pastes : problems Clays suspensions Rheology of pastes : problems Repulsive paste Repulsive pastes Repulsive paste How to measure f at rest Repulsive paste Repulsive paste : Beyond mean field approximation for the fludity Conclusion Polymer melt flow modelisation is well achieved ( for small shear rate at least) granular matter (dried) is nearly well understood ( at least good constitutive equations, based on physical arguments are able to reproduce experiments) Paste rheology understanding is poor because : ? most of them are complex systems – not well characterized ? even the simplest fluids (repulsive colloidal suspensions) exhibit complex physics Similar problems can be found for modeling plastic flow of solid polymer Thanks to * F. Lequeux Francois.lequeux@espci.fr h: solvant viscosity 10-3 Pa.s a: particle radius 10-6 m r: fluid density 103 kg/m3 Shear rate At the scale of the particles At the scale of the flow m: paste apparent viscosity 103 Pa.s Inertia effect are relevant only at very large scale, never at the particles scale Potentiel energy Potentiel energy Surface distance Surface distance Repulsive (requires chemistry) Attractive (most of the situations) Interaction strength Attractive Repulsive Non Brownian Brownian Grains in solution, ceramic paste Liquid Concrete Clays suspensions, yoghurt Tooth paste, paints, coating Interaction strength Attractive Repulsive Non Brownian Brownian Sand in water, ceramic paste Liquid Concrete Clays suspensions, yogh