3d打印技术制备cubtcabs复合材料及其应用 word格式.docxVIP

摘 要目前，越来越多的人关注具有独特结构的反应器、吸附剂和复合材料的开发。 特殊结构的反应器、吸附剂和催化剂可以有效改善反应活性、提高传热和传质效 率、降低压力降损失和方便规模化生产。结构反应器可以与含有多孔结构的催化 剂和吸附剂密切结合，包括含有微孔和介孔结构的有机多孔材料。Metal-organic frameworks（MOFs）是一种新型有机多孔骨架材料，该材料 通过金属离子和有机物分子的强配位键结合而成，具有多孔有序结构、极高的比 表面积，并含有多种官能团，使它成为在气体分离和储存、催化、能源储存、传 感器、污染物处理和生物医药等领域非常有前景的功能性材料。Cu-BTC，又称 Cu3BTC2 或 HKUST-1，是 MOFs 材料的一种，具有大比表面积，大孔体积，高 Lewis 酸性位，良好的化学稳定性。本论文利用 3D 打印技术将丙烯腈-苯乙烯-丁二烯共聚物（ABS）打印成框 架结构，然后通过原位生长逐层沉积的方法，将多孔金属有机骨架材料 Cu-BTC 负载到 ABS 框架上。生长在 ABS 上的 Cu-BTC 晶粒大小为 200-900 nm。所制备 的 Cu-BTC/ABS 复合材料能与反应器很好匹配，使得吸附不需要搅拌就可以进 行。利用 Cu-BTC /ABS 复合材料，亚甲基蓝能从水溶液中快速分离。对于亚甲 基蓝初始浓度为 10 mg/L 和 5 mg/L 的水溶液，在短短十分钟内，去除效率分别 能达到 93.3%和 98.3%。吸附亚甲基蓝后的 HKUST-1/ABS 复合材料，能从溶液 中直接取出，而不再需要离心过滤等分离操作。HKUST-1/ABS 复合材料能够吸 附脱附多次，具有一定的循环使用性能。ABS 塑料在经过多次吸附后也可以回 收再利用。关键词：3D 打印、三维成型、多孔有机骨架材料、MOFs、Cu-BTC、HKUST-1、 吸附剂ABSTRACTThe development of reactors, adsorbents and composites with unique structures has drawn great attention recently. These unique structures have advantages of improving reactivity, enhancing heat and mass transfer, lowering pressure drops and being easier to scale-up. Structured reactors are normally combined with porous materials like catalysts or adsorbents. In this regard, micro and meso inorganic porous materials have both been extensively applied.Metal-organic frameworks (MOFs) are a new type of porous materials that are fabricated by linking metal ions or clusters and organic molecules (linkers) by strong bonds. MOFs have ordered structures, permanent porosity, high surface area and can contain many different functional groups which make them useful for a variety of applications such as gas separation and storage, catalysis, energy storage, sensors, pollutant removal and biomedicine. Cu-BTC (also known as MOF-199, HKUST-1, or Cu3BTC2), one of the members of MOFs, was recently applied for gas storage and separation, catalysis and removal of pollutants due to its large surface area, big pore volume, high Lewis acidity, good chemical stability, and ability of coordinated with