5甲基1h四唑及25氨基1h四唑丙酸配位聚合物的合成与结构分析 word格式.docxVIP

AbstractThis thesis through hydrothermal method and solution method, using the 5-Methyl-1H-tetrazole (L1), the 2-(5-amino-1H-tetrazol-1-yl) propanoic acid(L2) and the 2-(5-amino-1H-tetrazol-1-yl) propionic acid (L3) With alkali metals, alkaline earth metals and transition metal coordination to synthesize 12 kinds of polymer which is divided into three series of synthetic what below reported before as follows: {[Ba (L1)2 (H2O)4] ?2H2O}n (1), [NaCa (L1)1.5 O0.5 ] n (2), [Ag(L1)]n (3), [Na (L2) (H2O)]n (4), [Ba (L2)2 (H2O)2 ? 2H2O]n (5), [Sr (L2)2 (H2O)2?2H2O]n (6), [Cd (L2)2 (H2O)2 ?2H2O]n (7), [Mn(L2)2(H2O)2?2H2O]n(8), [Cu(L2)2Cl]n(9),[Cu(L2)]n(10), [Mn0.5 (L3)]n (11), [Zn0.5 (L3)]n (12). The parsing analysis of single crystal structures found that the diversity of tetrazole ring nitrogen atom ligand and the coordination modes of carboxylic acid oxygen atoms. And the metal ionic radius size, different ionic species regularly effect to the structure of the complexes. Measuring the fluorescence properties of complexes.L1 and M (M = Na+, Ca2+, Ba2+, Ag+) in hydrothermal reaction conditions swells into three4namely 1D, 2D, 3D structure of the complexes. Complex 1 wherein Br-containing anion crystallized system centrosymmetric space group I-42m of the 3D structure of a cesium chloride-type topology ligand μ1,2,3 and μ1,2,3,4 two configurations bit pattern and metal complex; complex 2 without the addition of other anions to crystallize under the conditions of the chiral space group C2, 1D structures ligandμ1,2,3 bit pattern with the metal complex. Complex 3 NH + ions in the system containing crystallized centrosymmetric space group C2/c a 2D structure, with a special (41.82) 2D topology ligandμ1,2,,4 with coordination mode and the metal complex mode.L2 and M (M = Na+, Ba2+, Sr2+、Cd2+, Mn2+, Cu+, Cu2+) by hydrothermal method or solutionmethod synthesized seven complexes. Complex 4,7 and 8 are the complexes of the 3D structure. Complex 4 consists of two thre