ernd掺杂tio2基光阳极的改性及光电性能研究 word格式.docxVIP

AbstractTheadvantagesoflowcostandlowpollutionmakeDSSCbecomeanimportantdevelopingdirectionofthesolarcell.Becausephotoanodemadebynanomaterialsisoneoftheimportantcomponent,massiveresearchworkfocusontheanodematerialresearch.Thispapersmainresearchdirectionisanodematerialdopingmodification,prepareingandresearchingthe materialsofthe Er/NddopedTiO2electrodeandEr、Nco-dopedTiO2.Thepaperalsocarriedoutresearchonthesurfacemodificationofthephotoanode,contrastwiththeresearchonthephotoanodewithoutmodification.Er-dopedTiO2nanoparticlewithanatasehasbeenpreparedbyamethodsol-gel.Er-dopedTiO2 hasbeenstudiedbykindsofelectro-optic performancetests,suchasXRD、SEM、SPS、XPSandso on. Theresultssuggested thatdye-sensitizedsolarcellswithsuchEr-dopedTiO2haveachievedhigherconversionefficiencythanthatmadeofpureTiO2.Whenthe2at%Er-dopedTiO2powderisblendedwithpure TiO2 asanadditiveattheoptimalratioof7:5,thephotocurrentdensity,voltageandtheconversionefficiencyofthecellincreaseto13.38mAcm-2,0.78Vand6.63%,respectively.WhileDSSC with Nd-doped TiO2 and Er、N co-doped TiO2 have not achieved higherconversionefficiencythanthatmadeofpureTiO2.TogetthepurposeofraisingtheconversionefficiencyoftheDSSC,inthisexperimentwehasusedTiCl4tomodifythephotoanodethinfilmstoshortenthetransmissionpathofphotoinducedcarrierandimprovethestructureofthecell.Andintheend, wegotthepurpose.Keywords:dye-sensitizedsolarcell,rareearth,compositephotoanode,up-conversionluminescence,near-IRabsorption,目录摘要IAbstract II第一章绪论 11.1课题背景11.2 DSSC 的基本组织结构及基本工作原理3DSSC的组成部分41.3.1染料41.3.2 阳极材料51.3.3电解质71.3.4对电极7DSSC 的应用81.5 本论文的立题思想及工作内容9第二章实验条件及研究方法112.1 实验药品与仪器112.1.1实验仪器112.1.2实验药品112.2 评价染料敏化太阳能电池的参数122.2.1短路光电流密度（Jsc）和开路光电压（Voc）122.2.2 填充因子122.2.3 电池单色光光电转化效率132.2.4电池光电转换效率η(％)132.3 纳米二氧化钛的制备方法132.3.1 溶胶凝胶法132.3.2水热法132.3.3 电化学沉积法142.4 表征测试方法142.4.1 透射电子显微镜142.4.2 扫描电子显微镜142.4.3X-射线粉末衍射142.4.4 紫外-可见光谱分析142.4.5 电池光电性能测试152.4.6 交流阻抗性能测试152.5稀土掺杂纳米晶二氧化钛光阳极材料的制备152.6 复合电极的制备及电池组装162.6.1 复合光阳极的制备162.6.2阴极的制备172.6.3 染料和电解液的制