超支化聚合物合成、表征及端基光致变色改性研究-高分子化学与物理专业论文 word格式.docxVIP

河北大学硕士学位论文超支化聚合物合成、表征及端基光致变色改性研究姓名：王素娟申请学位级别：硕士专业：高分子化学与物理指导教师：巴信要摘要超支化聚合物具有低粘度无链缠绕良好的溶解性能等独特的特点且含有大量的活性端基 预计可在功能化材料 生物制药 临床医学等方面具有非常广泛的应用 本文合成了一种超支化聚(胺-酯) 并对其结构和性能进行 了表征 另外 还对另一种超支化聚(酰胺-酯)的端基进行功能化改性 得到了 具有光致变色性和酸碱变色性的超支化聚合物 同时利用紫外光谱对其变色性 进行了研究 本论文共分三章 其主要内容如下 第一章 绪论 对近年来超支化聚合物合成 表征及功能化研究现状进行了简 要回顾 第二章 AB3 型超支化聚胺-酯的合成及表征 以三羟甲基氨基甲烷和氯乙 酸乙酯为原料 通过控制反应条件合成了 AB3 型超支化聚胺-酯利用质谱粘度测定和热重分析对其单体结构聚合物的粘度和热稳定性进行了表征 第三章超支化聚(酰胺-酯)的端基光致变色改性研究用 4-4 -二甲氨基苯 基偶氮甲酸对一种超支化聚酰胺-酯的末端羟基进行功能化改性得到了 一种具有光致变色性和酸碱变色性的超支化聚合物并利用紫外光谱对其变色性进行了研究 关键词超支化聚胺-酯 合成及表征 超支化聚(酰胺-酯) 光致变色 ABSTACT The hyperbranched polymers have been attracted considerable attention due to its highly branched units with peculiar properties, such as low melt viscosity, good dissolubility, non-entanglement and a large number of active end groups. Hyperbranched polymers were widely used in many fields,such as functional materials, c linical medicine, supramolecular chemistry, biochemistry and pharmaceutical industry.In the paper, a kind of hyperbranched poly(amine-ester)s were synthesized and characterized .In addition, a kind of photochromic hyperbranched polymer were synthesized bythe modification of hyperbranched poly(amide-ester)s and characterized by UV techniques. There are three chapters in this paper, and the main contents are as following: In chapter 1, the overviews of the progress in hyperbranched polymers were given. In chapter 2, synthesis and characterization of the AB3 type hyperbranched poly(amine-ester)s.The AB3 type hyperbranched poly(amine-ester)s were synthesized by the reaction of chloroacetidin with tri(hydroxymethyl) aminomethane on the correct condition. This polymer were characterized by MS, TG and viscosity measurement. In chapter 3, Study on the end photochromic modification of hyperbranched poly(amide-ester)s. A kind of photochromic hyperbranched polymer were synthesized by the end group modification of hyperbranched poly(amide-ester)s. The polymer were characterized