凝胶注模氮化硅基复合陶瓷的制备工艺与性能研究-材料学专业论文 word格式.docxVIP

Si3N4basedceramicswerepreparedbygelcastingwithAlPO4assintering addtitive.Withtheincreaseofsinteringtemperature,therelativedensityofwas enhancedto60.4%.Thebendingstrengthandthecontentofβ-Si3N4ofcompositeswereincreasedupto149.8MPaand24.3%repectively,andthethermalexpansioncoefficientwasdecrasedto2.40×10-6K-1.Moreover,dielectricconstantanddielectriclossofSi3N4basedceramicsincreasedupto4.66and1.3×10-2,respectively.Soithasagoodintegratedperformance.Comparedwithgelcasting,Si3N4basedceramicsmadebyCIPhashigherbendingstrength(229.2MPa),becauseofthehigerrelativedensity(67.5%)andcontentofβ-Si3N4(85.3%),butisdegradedinthermalexpansion(αk=2.69×10-6K-1)anddielectricproperties(ε=6.47,tgδ=2.1×10-2).Keywords:gelcasting;agarose,siliconnitridebasedceramic,mechnicalproperties,dielectricproperties- III-目录摘要...........................................................................................................................IAbstract......................................................................................................................II第1 章绪论............................................................................................................11.1 前言...................................................................................................................11.2 氮化硅材料概述...............................................................................................21.2.1Si3N4 晶体结构和性质21.2.2Si3N4 陶瓷的性能与应用31.2.3Si3N4 陶瓷天线罩材料的研究进展51.3 凝胶注模成型方法...........................................................................................71.3.1 凝胶注模成型工艺研究概况....................................................................71.3.2凝胶注模成型在Si3N4基复合陶瓷制备过程中的应用101.3.3 凝胶注模成型工艺中低毒性凝胶体系的发展状况..............................111.4 本文的目的、意义及主要研究内容.............................................................131.4.1 研究的目的和意义..................................................................................131.4.2 主要研究内容...............................................................