羟丙基-β-环糊精对多氯联苯的增溶研究-市政工程专业论文 word格式.docx

硕士学位论文摘要。，多氯联苯是一类广泛分布的环境有机污染物修复被污染的土，，、、壤保障人类健康以实现社会的可持续性发展是环境科研领域非常具有理论。。和实际意义的课题之一本文简介了多氯联苯的物理化学性质环境毒性环境、。吸附行为环境迁移转化行为及其污染状况探讨了表面活性剂增溶和环糊精增，溶的机理综述了疏水有机污染物的增溶研究进展本文研究了轻丙基一一环糊精对，’一二氯联苯，’、，’，，’四氯联苯，’，，’、，’，，’一四氯联苯，’，，’、，’，，’，，’一六氯联苯，’，，’，，’和的增溶。’’和在’’’。溶液中的溶解在天基本达到平衡当环糊精浓度为时，，’、，’，，’、，’，，’、，’，，’，，’和的表观溶解度分别增加、、、了倍倍倍倍和倍种同族体和。，，的溶解度都随浓度的增加而线性增加与种同族体均生成。。的包结物环糊精空腔与的疏水作用是产生增溶作用的基础的疏，’水性越强对之增溶效果越好的空腔与分子的空间匹配程度。是影响对增溶效果的重要因素空腔与，分子的空间匹’配程度好于空腔与，’，，’分子、，’，，’分子分、，’，，’，，’，，子的空间匹配程度因此对，的实际增溶效果好于仅根据其疏水性。所确定的增溶效果种同族体在溶质体系中的摩尔溶解率平均只有单溶质体系，，’的在体系中的只有单溶质体系的共溶。质降低了对的增溶效果对于，的增溶能力与聚氧乙烯，型非离子表面活性剂非常接近对于，’，，’、，’，，’，，’。和。的增溶能力匕要弱关键词多氯联苯轻丙基一一环糊精增溶表观溶解度九︺轻丙基一一环糊精对多氯联苯的增溶研究，，，，，’，，’，，’，，’，，’，，’，，’，，’一一，’，，’，’，，’，，’，’，，’，，’，，’，，’，，’，，’，，’，，，，，，’，’，，’，，’，，’，’，，’，，’，，’一一，一，一扮不硕士学位论文，’，，’，，’，，’，，’经丙基一一环糊精对多氯联苯的增溶研究插图索引图多氯联苯分子的结构式·························································……一图的分子结构示意图……················································，········图表面活性剂的分子结构示意图……················································图客体分子取代环糊精高能水示意图……··········································图的分子结构示意图……······················································图离心转速对溶解度的影响……··········，··································图在中溶解平衡时间的确定……····································图为时，图为时，图为时，’的分析图……·································’的分析图……·································’的分析图……·································’图为时，的分析图… …······························’，’图为时，，的分析图……························图为时，’，，’的分析图……························图为时，，’’ ，’，，的分析图……·····················图为时的分析图……·····················’图对，的增溶关系图……··········································’，’图对，，的增溶关系图··········· ······················ ···……图对，，’，，’的增溶关系图……·······································图对，’，，，’，’的增溶关系图……·································图对的增溶关系图……····································图本试验中同族体的与、的线性关系……············图疏水有机物的与的线性关系……···························图空间匹配程度对增溶效果的影响……························图，’的分子尺寸示意图……·····，··，··········································图为时溶质体系