具有光、磁和铁电性质的手性分子基稀土功能材料的构筑与分析-材料学专业论文 word格式.docx

IV. 以非手性的 β - 二酮有机化合物 acetylacetone (acac) 与稀土离子反应，通过适当的合成方法和分子内的自组装，制得了两个手性的十四核簇合物 Ln14(μ4-OH)2(μ3-OH)16(μ-η2-acac)8(η2-acac)16?6H2O [ Ln = Tb (15), Dy (16) ]。X-ray 单晶衍 射仪测试表明两种配合物结晶于极性C2 空间群；光致发光性质测试表明他们在可见光 区有良好的特定稀土离子的特征荧光；磁性测试表明其分子内存在稀土离子间的反铁磁 耦合作用。关键词：手性；对映体；荧光；磁性；铁电；功能材料ABSTRACTMolecule-based multifunctional materials, as a novel research project in molecular materials field, have drawn considerable attention in recent years. Multifunctional materials imply that the material possess more than two physical properties, such as optical activity, ferroelectricity, magnetism, luminescence and so on. In this thesis, utilized the high luminescent efficiency and high color purity of the lanthanide ions, a series of lanthanide β – diketone molecule-based materials with well luminescence and ferroelectricity have been designed and synthesized by the introducing of chiral organic ligands. In summary, the thesis consists of four sections as follows:Two pairs of enantiomers, L2NR:(-)-4,5-pinene bipyridine (1) ; L2NS:(+)-4,5-pinene bipyridine(2) and L4NR:(-)-pinene pyrazine derivative (3), L4NS:(+)-pinene pyrazine derivative (4), have been prepared and characterized by IR, GC-MS, NMR, circular dichroism (CD) spectra and X-ray single crystal diffractometer. They are mirror images in the observed CD spectra, which further confirm their enantiomers nature.Using the β - diketone organic compounds 4,4,4-Trifluoro-1-(2-thienyl)-1,3- butanedione(Htta) as the first ligand and L2NR:(-)-4,5-pinene bipyridine (1) or L2NS:(+)-4,5-pinene bipyridine (2) as the second ligand to react with lanthanide ions, three novel pairs of enantiomers, Nd(tta)3·L2NR (5), Nd(tta)3·L2NS (6) and Yb(tta)3·L2NR (7), Yb(tta)3·L2NS (8) and Er(tta)3·L2NR (9) , Er(tta)3·L2NS (10), have been successfully synthesized. Single crystal structure analysis reveals that complexes crystallize in chiral and polar space group P21 of monoclinic system. The results of ferroelectric and photoluminescent measurement sh