做太阳能电池需要了解的TCO衬底知识TCO_Glass_for_Thin_Film_PV.pptVIP

TCO Glass for Thin Film PV Content Key Parameters of TCO Glass Technology Category and Process Typical Glass Size Opportunity and Challenges Key Parameters of TCO Glass Key Parameters of TCO Glass Transparent rate≥80%(400nm-1100nm) Sheet Resistance≤10Ω/□ Haze ratio≥30%(400nm-800nm) Uniformity on large size panel High Reliability Factors that impact SJ light IV curve (LIV) Jsc is determined by the max photocurrent Dead zone lowered the Isc by 3% (Laser scribe) Collection coeff (percentage of photocurrent collected under bias voltage) will fundamentally limit FF (which trend to be the same for different initial value after LID). Diode current will determine the Voc. Rs and Rsh will further lower the FF. Absorption impact to the solar cell spectrum response TCO absorption will impact of the Jsc of solar cell. Two different kinds of TCO with different extinction coefficient, which lead to a change of Jsc. Glass absorption will also impact Jsc. TCO sheet resistance impact TCO sheet resistance will impact of the FF of solar cell. Increase of TCO sheet resistance will lower the module Eff. (with a slope of -0.03% per ohm increase) Haze impact to the solar cell spectrum response TCO Haze factor will impact of the Jsc of solar cell. Left figure: Haze factor vs. wavelength. (haze #1 is the haze for NSG SL) Right figure: Increased Haze factor leads to higher current. Reliability Technology Category and Process Thin Film PV Structure List a-Si and uc-Si SnO2:F on low iron glass ZnO:Al or ZnO:B on low iron glass ITO for flexible solar cell CdTe:SnO2:F on soda lime glass Process: SnO2:F----On line APCVD ( NSG and AGC) Off line APCVD (Nanbo) ZnO:Al ----PVD+Etching (Xingyi) RPD+Etching (SHI) ZnO:B-----On line LPCVD (Oerlikon) ITO---------PVD and RPD ZnO Vs SnO2 Typical Glass Size Industry Trend:1400*1100*3.2mm(4mm) or 1245*635*3.2mm or 1300*1100*3mm (4mm) or 1200*600*3.2mm O