淀粉基硬炭微球的制备及电化学性能研究-化学工程与技术;化学工艺专业论文.pdf.docx

efficiency of 80.4%. It was found that the potato starch based spherical hard carbons carbonized at higher temperatures showed better high-rate discharge performances.Discharge curves of the anodic carbon material carbonized at 1300℃, almost did notchange with increasing discharge rates. Discharge specific capacities of this sample had high preserved percentages with increasing discharge rates. Even at 10C, the discharge specific capacity remained 88.7% of that at 0.1C. Results also showed the starch based spherical carbon material possessed good cyclic property, excellent PC based electrolyte compatibility and showed stable electrochemical property after long-time storage in atmosphere.Starting from varied starches, hard carbon spherules with different morphologies and different particle sizes were prepared. It was found that the structures and element contents of the prepared carbons almost did not change with different starches. Electrochemical properties mainly affected by the particle sizes of the hard carbon spherules. Prepared carbon spherules with smaller particle sizes showed high reversible specific capacities and possessed better high-rate discharge performances. Among spherical hard carbon anodic materials prepared from different starches, rice starch based one had the smallest particle sizes and showed good electrochemical performances. Discharged at 0.1C the rice starch based anodic material had a specific capacity of 582.3mAh/g and an initial efficiency of 78.08%; discharged at 10C this anodic material also preserved a specific capacity of 478.2mAh/g.KEY WORDS ： starches, stabilization treatment, spherical hard carbons, Li-ion secondary batteries, anodic materials, electrochemical properties目录第一章 文献综述 ............................................................................................................................ 11.1 锂离子电子电池概述 ....................................................................................................... 11.1.1 锂离