铁及其化合物强化焦化废水厌氧处理研究-环境工程专业论文.docx

铁及其化合物强化焦化废水厌氧处理研究Study on zero··valent··iron and ferric iron enhanced anaerobic biological treatment of coking wastewaterAbstractCoking wastewater iS a kind of typical lindustrial wastewater which contains plenty of refractory organic contaminants．Due to the toxicity and poor biodegradability of coking wastewater，the performance of biological treatment of actual coking wastewater is generallyunsatisfied．As a high．efficient and low．cost biological treatment technology．anaerobicbiological reactor has been widespreadly used for wastewater treatment．However，with respect to the treatment of actual coking wastewater，the long start．uD time of仃aditional anaerobic reactor and the weak ability resisting the change of organic loading rate limits the performance of anaerobic reactor．Herein，zero—valent-iron(zvo and magnetite(Fe304)were added in the reactors and the enhanced performance ofthe reactors was investigated．Besides．The effects onmicrobial communities in the reactors were alSO studied．Our experiments provide theoretical evidences for further practical applications of ZVI enhanced anaerobic biological reactor and magnetite enhanced anaerobic biological reactor for the treatment of coking wastewater．Therefore．three reactors were operated to study on the different performance ofthe UASB． ZVI．UASB．and magnetite．UASB．Microbial communities of all three reactors were also investigated．The conclusions were listed as below：(1)The start．uD time of the ZVI enhanced reactor Was effectively reduced compared tothat of UASB．The sludge acclimatization was completed in 80 days．The hydraulic retention time(HRT)was 24h．The temperature was 3 5+1 oC and the CODcr of influent was about 2000 mg／L．The CODfr removal emciency of the ZVI．UASB efnuent was 69％，which was significantly higher than that ofthe UASB effluent(CODcr removal efficiency Was 38％)．Witll respect to the biodegradability，the BODs／CODcr(B／C)of influent was 0．1 54，which indicated the poor biodegradability ofcoking wastewater．The