新型双取代聚炔类共轭聚合物荧光探针的设计、合成及其应用-有机化学专业论文.docx

研究生优秀毕业论文对Cu2+离子的识别。 关键词：双取代聚炔；共轭聚合物荧光探针；碘离子；汞离子；铜离 子；草甘膦万方数据AbslractAbstractFluorescent probes is realized mainly through its colour or fluorescence changes for a specific qualitative or quantitative targets，and has several important advantages such as high selectivity,high sensitivity，short reaction times and convenient operation． Considerable research interests have been focused on the development of fluorescent sensors for environmental monitoring and bio·imaging．Conjugated polymer-basedfluorescent probes display several important advantages．For instance，signal amplification，easily fabricated into devices and combination ofdifferent outputs，CPFshave attracted great attention．Based on this，we have designed and synthesized two kinds of disubstituted polyacetylene-based fluorescent probes，and studied the properties of selective recognition for target compounds．Meanwhile，we made them to fluorescent strips，and achieved some interesting results．All the target compounds obtained were characterized by FI．IR,1H NMR,13C NMR and LC．MS．1．Brief overview of the design principles of fluorescent sensors，the advantages，research history and status of conjugated polymers fluorescent sensors．2．We design and synthesis a new disubstituted polyacetylene P1 bearing carbazole moieties．Iodine as a typical heavy atoms，has high nuclear charge．From the literature， heavy atom effect of r toward N-atom in carbazole is the presumable reason for the fluorescence quenching．ARer the addition of I．，which led to the P1 fluorescence quenching，and the color ofthe solution also changed from colorless to yellow．It is wellknown that the association constants between iodine and mercury ions are very high(8．3x1023 for Hgl2 and 6．31x1029 for[Hgl4]2_)．and P1／I’complexes with H矿Call be detected．After the addition of ri92+,Pl厅fluorescence is restored，as well as solutionsfrom yellow to colorless．In order to further improve the convenience of testing，we made P 1 ito fluorescent strips，and succeeded in reporting