新型棉用耐久阻燃整理剂的合成及应用-纺织化学与染整工程专业论文.docx

缈东华大学硕士学位论文大普弟寻过对制备的阻燃剂的外观形态、颜色、粘性、有效组分含量及粒径等测试了解阻燃剂各中物理性质，并通过红外、元素分析等手段鉴定了所合成化合物化学分子结构，对合成过程各因素进行优化分析，确定了最佳的合成路线。在此基础上，对制备的反应性阻燃剂进行了应用性能研究，选择在纯棉纱卡织物上采用普通的轧烘焙后整理，依次改变阻燃剂用量、焙烘温度、pH值、催化剂用量、交联剂用量、织物浸液时间、水洗次数及整理后织物的游离甲醛含量等影响因素，结合炭长、极限氧指数、断裂强度、色变及折皱回复角等的变化，确定出了该阻燃剂的最佳整理工艺。在阻燃性能测试同时还进行了此整理后棉织物的抗皱性能测试，发现此长链阻燃剂不仅能有效提高织物阻燃效果且对棉织物有一定的抗皱效果，可作为阻燃一抗皱多功能整理剂开发应用。此外，本论文通过对整理前后的织物的DSC、TGA、扫描电镜、元素分析等测试与分析，探讨了棉织物的燃烧分解机理及阻燃剂整理棉织物的阻燃原理，阐述了该类阻燃剂兼具凝聚相阻燃原理、气相阻燃原理、膨胀型阻燃原理及协同阻燃原理。关键词:耐久，阻燃剂，棉，三聚氰胺，多烯多胺，嶙酸醋缈AbstraCt弟寻大普SynihesisandAPPlicationofw 叔sh一fastN ovelFlam eRet盯dantOnCottonAbstractWith the in一depth study offlame一retardant textiles steP一by一steP，desPite halogen-eoniaining flameretardanthasgood inflamingretarding result，thehalogen一eontainflame retardant willgradually be rePlaced by halogen一free ones beeause it15eonsidered thatitw illreleasealargenum berof susPeeted toxicgasatthetimeofusing and eom bustion Proeess，the existenee ofseeondary Pollution 15 an otherseruPled.TheelassofPhosPhorus一eoniaining fiam eretardant，asaw iderangeofgoodapPlication ofhalogen一freeflameretardants，hasbeen thehotsPotsofglobalstudy.Commoncottonflameretardantsonmarketarem ostlyeonfinedfortheun创endlyexistenee to environm entofkeePing releasing formaldehyde，and thisresearch 15eom m itted to environm enially friendly and water-fast eotton use of flameretardants.Thebasiestructureoftheskeletonw ithm elallllneandPolyalkylene一Polyam ineswereresPeetivelydesignedandsynthesizedfor thesPeeifieationof anti一wrlnkleandflame一retarding.Thebasicstructureof theanti一wrinkledurableflame一retardantfinishing agentw assynthesized bytw o m ethodsw ithtwo ravvm aterials，one 15m elam ine，another15m elam ine form aldehyde resin:Aseries ofm ulti一basie framewo rk structure ofPolyalkylene一Polyam ines durable theflame retardantswere synthesized by ehanging the ratio ofraw m aterialsandehangingfunetionalgrouPsresPectivelyinthelatterP叭ofthethesis.ThePhysiealnature ofthe flame retardantswere tested by the apPearance ofthe