稀土荧光材料的制备、光谱特性及其应用研究-光学工程专业论文.docx

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稀土荧光材料的制备、光谱特性及其应用研究-光学工程专业论文.docx

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稀土荧光材料的制备、光谱特性及其应用研究-光学工程专业论文

AbstractAstherare-earthionsareofaveryrichelectronicenergylevel,rare-earthdopedfluorescentmaterialsarewidelyusedinfluorescentlight,display,imaging,opticalinformationtransmission,solarphotovoltaicconversion,lasers,nuclearphysicsandradiationdetectionandrecording,andmanyotherfields.Amongthese,thewhiteLEDlighting,fluorescentsensingarethenewandemergingtechnologiesofrare-earthdopedfluorescentmaterials,andwehavearesearchonthesetwoareas.Y2O3:Er,Ybnanocrystallineswerepreparedbyliquidcombustionmethod.ThesampleswerecharacterizedbypowerX-raydiffraction(XRD),and photoluminescentemissionspectra.BasedonthefluorescenceintensityratiomodelofY2O3:Er,Yb sample,aclassofhighprecisionmethods(fluorescentspectroscopicmethods)areintroducedtomeasuretheBoltzmannconstant.PopulationofelectronsinthermalcoupledlevelsofphosphorscanbedescribedwithBoltzmanndistribution.Basedon temperaturedependentphotoluminescenceofaphosphor,Boltzmannconstantisderivedfromtherelationshipbetweenmeasuredrelativeintensityandtemperature.Relationshipbetween kBandh*c(Planckconstant multiplyinglightspeedinvacuum) isderivedfromexperimentalmeasurement.ThedeterminedBoltzmannconstantshows~0.2%divergenceupontheCODATArecommendedvalueintheyear2006.In thisarticle,thetemperaturecharactersofY2O3:Er,Ybphosphorswereanalysed.Inthisarticle,Eu-dopednanocrystallineswerepreparedbyliquidcombustionmethod.ThesampleswerecharacterizedbypowerX-raydiffraction(XRD),and photoluminescentemission spectra. The charge transfer energiesofthesamples differ fromtheenvironmentalfactors:differentsamples,differentenvironmentalfactors(namelythedifferentcrystalfieldenvironmentsofrareearthions), differentlocations ofthechargetransferband,differentchargetransferenergies.Basedonthe5D0?7F1sub-energyleveltransitionfluorescenceintensityratiomodelofEu-dopedsample,thevariableYBO3:EutemperaturespectraswereusedtomeasuretheBoltzmannconstant.ThedeterminedBoltzmannconstantshows~0.2%divergenceupontheCODATArecommendedvalue.Then, theapplicationofthe red emissionof theEu-doped