毕业论文--CdSe量子点及其核壳纳米晶的自组装.docVIP

摘 要 本文用热注入法合成了CdSe量子点，然后分别用正硅酸乙酯(TEOS)和氨丙基三乙氧基硅烷(APS)作为修饰剂进行CdSe量子点的自组装，并用三辛基膦(TOP)作为配体制备了CdSe/ZnS量子点。通过X射线衍射仪、透射电子显微镜、荧光光谱仪、紫外可见近红外光谱仪等手段对制备样品进行了表征。结果表明：CdSe量子点的荧光发射峰波长随反应时间的延长而增大；其荧光强度随着放置时间的延长发生衰减，且荧光发射峰波长先发生红移后发生蓝移，说明这种方法制备的CdSe量子点不稳定。加入正硅酸乙酯(TEOS)和1μL氨丙基三乙氧基硅烷(APS)使CdSe量子点发生了团聚，加入1.5μL氨丙基三乙氧基硅烷(APS)后CdSe量子点进行了自组装。以不同荧光发射峰波长的CdSe量子点为内核制备的CdSe/ZnS的波长随内核波长的增大而增大，且与内核波长相比均出现了红移，红移量随CdSe量子点波长的增大而减小，说明CdSe内核决定了其荧光性质，而ZnS外壳只起修饰和改善作用，并且ZnS层随CdSe量子点粒径的减小而变厚。 关键词：CdSe；量子点；自组装；核壳纳米晶 ABSTRACT In this thesis, the CdSe quantum dots were synthesized by hot injection synthesis. tetraethyl orthosilicate (TEOS) and aminopropyl triethoxysilane (APS) were used as modifiers for self-assembly of CdSe quantum dots respectively. CdSe/ZnS quantum dots were obtained by using trioctylphosphine as the ligand. The samples prepared were characterized by XRD,TEM, fluorescence spectroscope and UV-Vis-NIR recording spectrophotometer. It was found that the PL peak wavelength of CdSe quantum dots increases with the increasing of the reaction time; its PL intensity decrease with the increasing of store time. At the same time, the PL peak wavelength exhibits a red shift first and then a blue shift occurs.The results indicate that CdSe quantum dots prepared by this synthesis are unstable. In the process of self-assembly of CdSe quantum dots, tetraethyl orthosilicate (TEOS) or 1μL of aminopropyl triethoxysilane (APS) cause agglomeration and 1.5μL of aminopropyl triethoxysilane (APS) leads to self-assembly. CdSe quantum dots of different PL peak wavelength were used as cores to synthetize CdSe/ZnS quantum dots. The wavelength of CdSe/ZnS increases with the increase of the wavelength of CdSe quantum dots,and the PL peak wavelength exhibits a red shift. Red shift decreases with the increase of CdSe quantum dots wavelength. The results indicate that CdSe cores determine fluorescence properties of CdSe/ZnS and ZnS shell only plays the role of modification and improvement.In addition, ZnS shell become