热处理对太阳能电池粉末CuZnSnSSe显微结构与拉曼光谱特性研究.PDFVIP

熱處理對太陽能電池粉末CuZnSnSSe 顯微結構與拉曼光譜特性研究 1 1* 1 1,2 劉泰翔 洪飛義 呂傳盛 陳冠仁 1 Department of Materials Science and Engineering, Institute of Nanotechnology and Microsystems Engineering, Center for Micro/Nano Science and Engineering, National Cheng Kung University, Tainan 701, TAIWAN. 2 The Instrument Center, National Cheng Kung University, Tainan 701, TAIWAN. * Corresponding author Email: fyhung@mail.ncku.edu.tw Tel: 886-6-2757575-31395 Fax: 886-6-2745885 Abstract The Cu2SnZn(S+Se)4 (CZTSSe) is an excellent absorber material for the solar cells. This study obtained the CZTSSe powders through solid state reactions by the ball milling and sintering processes from elemental Cu, Zn, Sn, S, and Se without using either polluting chemicals or expensive vacuum facilities. Ratios of S/ S+Se in CZTSSe were controlled from 0 to 1. The results showed the 2 step sintering treatments (400℃for 1 hr and then 700℃for 1 hr) could stabilize the composition of powders. The crystallized intensity of CZTS matrix decreased with increasing Se content. Adding Se content could restrain the SnS phase to form and had reduced the resistance of present absorber layer. In addition, Raman data confirmed both CZTS and CZTSe were existed in CZTSSe matrix. Keywords: CuZnSnSSe (CZTSS), Solar cells, Raman, Se doped. 1.前言 CZTS (Cu Zn Sn S ) 近年來受到矚目 [1-2]由於， Zn 與Sn容易取得 且相 2 1 1 4 較於 CIGS 之 In 與Ga 成本高昂，被認為具有取代CIGS潛力 。文獻發現[3-4] ， 使用 co-sputter 、電鍍沉積…等方法來形成的CZTS 薄膜，因製程成本高 ，使 得發展受到侷限。本研究使用固態粉末機械研磨法合成 CZTS 粉末具有成本 優勢與結構穩定特性 。考量 CZTS所使用 材料是Cu, Zn, Sn, S ，而S沸點 低，在高溫熱處理下容易變成氣體逸散而不易控制 ；傳統 CIGS使用的 Se 粉 末其沸點較S高 [5] ，對於四元CZTS 薄膜性質穩定具有貢獻。因此 ，本文則 在 CZTS 粉末系統中 控制Cu, Zn,