cuo审审ceo2al2o3催化剂的制备及催化氧化甲苯和二甲苯的研究word格式论文.docxVIP

AbstractCatalytic oxidation technology was a new method on the degradation of volatile organic compounds, showing advantages of lower reaction temperature and less consumption of energy. Much attention has been paid to catalytic oxidation treating organic exhaust gas in the air. The preparation of highly active and stable catalyst was the key to the research of catalytic oxidation technology.The catalysts were prepared by impregnation methods, using γ-Al2O3 or SiO2 as carriers, CuO as active components, adding lanthanon Ce. Using the catalytic oxidation of toluene as the model reaction, dynamic catalytic oxidation reaction system was established. The activity of catalysts and the influence of reaction conditions were investigated with this reaction system.In all kinds of catalysts using different carriers, the one using γ-Al2O3 (60～80mesh) as carrier had the best ability on the degradation of toluene. Compared with CuO/Al2O3 catalyst, CuO-CeO2/Al2O3 catalyst which was added Ce had lower temperature of initial combustion and complete oxidation, the prepared parameters were optimized and the results showed that the catalyst with 5wt% Cu loading amount, the 1:1 rate of Cu/Ce and calcined at 500℃ for 6 hours has the highest catalytic activity.There were many influencing factors on catalytic capability. Three main factors (reacting temperature, airspeed, inlet concentration) in the catalytic oxidation reaction were researched to toluene and xylene. In test range, the optimal airspeed of toluene for CuO-CeO2/Al2O3 was 8000h-1, and it was 6000h-1 for CuO/Al2O3. The results of influencing factors experiment on catalytic capability of xylene were similar with that of toluene, and the optimal airspeed of xylene for CuO-CeO2/Al2O3 and CuO/Al2O3 was 8000h-1. Compared with the experiment of catalytic oxidation toluene, the xylene removal efficiency of CuO/Al2O3 was preferable, and it was over 90% in different airspeed and inlet concentration. It could achieve the removal purpos