用SZorb技术脱硫几乎能完全避免成品油辛烷值的损失.PPTVIP

S Zorb? 吸附脱硫技术:能同时解决 FCC 汽油脱硫和辛烷值增加的先进技术 Dayong Dong Technology Licensing Director Ricky Snelling, PhD Product Director 演讲内容提要 解决硫再次反应的问题 S Zorb SRT 工艺的长处 S Zorb SRT 工艺的特别效应 以低成本脱硫至10ppm以下 维持最低限度的成品汽油辛烷值的损失 极低限度的氢耗 极低限度（接近于零）的液流损失 除脱硫外，对进料的其他组成几乎完全没有影响 操作周期可完全 配合FCC 装置 Ferndale 工业装置的实际效应 汽油脱硫过程中保持辛烷值 传统加氢脱硫技术都避免不了相当程度的成品油辛烷值损失 烯烃加氢饱和是辛烷值损失的主要原因 用加氢脱硫技术脱硫到95%时，成品汽油的RON值就会降低至少2个单位 用S Zorb技术脱硫几乎能完全避免成品油辛烷值的损失 S Zorb能在烯烃饱和活性极低的条件下有效地脱硫 少量的烯烃饱和反应还是难免的 在S Zorb工艺上使用适量的辛烷值增效添加剂能达到使成品油辛烷值不变甚至辛烷值增加的效用 此添加剂的应用使S Zorb工艺的经济性更高 此反应的副产品还能用来做烷基油的原料 一般辛烷值增效的手段 加氢异构 加氢裂化 烷烃异构 把烯烃先分离后再加氢脱硫* * 需要添加设备，操作费用也可能提高 调配选择性异构和裂化反应 工业化数据平均脱硫率 = 99.0% 辛烷值增效催化剂为什么应该用在S Zorb SRT 而不是用在FCC装置? S Zorb SRT操作温度较低 ? 裂化反应少，轻烃产率低 S Zorb SRT 催化剂置换速率较 FCC低 Zorb SRT 再生条件缓和? 催化剂使用寿命长 FCC汽油原料“清洁 ” (无金属及其它毒物等) 磨损率非常低 不影响 FCC 处理量 (比如湿气压缩机WGC的限制) 使炼厂在汽油辛烷值调配的选择上有更大的灵活性 经济效应更好 Refinery Flexibility ConocoPhillips experience with process enhancing catalysts has not been limited to the laboratory and pilot scale. Third party commercial zeolite catalysts have been used in the S Zorb unit located in Borger, Texas, USA for the past two years. Likewise, the S Zorb unit located in Ferndale, Washington, USA has been using an octane enhancing zeolite catalyst for the last nine months. Experience to date has been very positive and has demonstrated a good octane boost with only a slight decrease in gasoline yield. Depending on feedstock properties, anywhere from 0.5 to 1.0 (R+M)/2 increases have been achieved relative to baseline operation without the catalyst. The resulting gasoline volume loss is typically less than 0.2 vol%. In addition, the zeolite catalysts have shown excellent compatibility with the S Zorb sorbent and process. No effect on sorbent attrition has been observed. The catalyst is continuously regenerated along with the sorbent and shows no evidence of activity degradation over time. This is not surprising since the S Zorb reaction and regeneration conditions are much less severe than in ty