fe2o3bi2o2co3复合纳米材料的合成及其光催化性质的研究word格式论文.docx

ABSTRACTInrecentyears,bismuthoxidebasedmaterials,anovelkindofsemiconductor, havebeenintensivelystudiedduetoitsspeciallayeredstructureandoutstanding chemicalandphysicalproperties.Therefore,theapplicationofbismuthoxidebased materialsisalsoverybroad,suchassolarcells,sensors,ferroelectricmaterials, nonlinear optical materials and optical catalysis.As a representative member ofAurivillius-relatedoxidematerials,theBi2O2CO3 isatypical“sillén”phase,inwhich(Bi2O2)2+layersand(CO3)2-layersarealternatelyarrangedwiththeplaneofthe(CO3)2- grouporthogonaltotheplaneofthelayer.Thestrong intrinsicelectricfieldbetweenthe bismuthoxidelayerandthecarbonoxidelayercaneffectivelypromotetheseparation ofphoto-generatedelectronandholepairs.So,theBi2O2CO3photocatalystshowsgood photocatalyticactivity.Inthispaper,Bi2O2CO3photocatalysthasbeensynthesizedby thesimplymodifiedhydrothermalmethod.Then,theeffetsoftheseveralkindsof organicdyesonitsphotocatalyticpropertieshavebeensystematicallystudied. Afterwards,Bi2O2CO3hasshowngoodphotocatalyticperformancein recentyears. However,itsbandgapisrelativelylarge.Therefore,wechoosethevisiblelight responseFe2O3coupledwithBi2O2CO3toenlargethelightabsorbrange. Fe2O3/Bi2O2CO3compositecatalystwiththedifferentmolarratioswasalsosynthesized bythefacileone-stepmodifiedhydrothermalmethod.Themaincontentsofthispaper can besummarized asfollows:Bi2O2CO3photocatalysthasbeensynthesizedbyasimplymodifiedhydrothermal method.Theas-preparedsamplewascharacterizedbyXRD,TG-DSC,SEM,TEM, XPSandUV-vistoevaluatetheelements,structure,morphology,thermalstabilityand opticalproperties.RhodamineB (RhB),MethylOrange(MO)andMethyleneBlue(MB) wereseparatelyusedasthemodelsubstancetoevaluatethephotocatalyticactivityof theBi2O2CO3photocatalystunderthesimulatedsunlight.Theresultsindicatedthatthe pureBi2O2CO3 exhibitedmuchhigherphotocatalyticactivityfordegradingRhBthan theMOandMB.In50min,50mLRhodamineBsolutionwiththeconcentrationabout2 × 10-5M can bephotodegraded completely.Here,visiblelightabsorbing