fe3o4@c复合微球制备及其在电磁波吸收和电化学领域中应用word格式论文.docx

优秀毕业论文 精品参考文献资料 Abstract This article sythesised Fe3O4@C composites，which was based on Fe3O4/C composites, aimed at solving the problem of disproportion and uncontrollability of carbon content when composing Fe3O4 with carbon. Fe3O4 microspheres synthesized by hydro-thermal method was used as basis, Fe3O4@C, with 500 nm Fe3O4 microspheres as cores have been successfully prepared through in situ polymerization of phenolic resin on the Fe3O4 surface and subsequent high-temperature carbonization. The thickness of carbon shell, from 20 nm to 60 nm, can be well controlled by modulating the weight ratio of resorcinol and Fe3O4 microspheres. It was used to have application in microwave absorption and electrochemistry fields. Carbon microspheres hollow with the thinnest carbon layer were ultimately obtained on the basis of the Fe3O4@C composites, and were applied to supercapacitor field. In this article, X-ray diffraction was used to characterize the crystalling phase of the materials, and the results showed that the original crystalling phase of the compound microballoon of Fe3O4@C can be maintained, when carbonized under 600 oC and 650 oC, while under 700 oC would be altered. Scanning electronic microscope and transmission electronic microscope were applied to characterize the appearance and the carbon thickness of the materials, and the results proved that the thickness of carbon shell can be well controlled by modulating the weight ratio of resorcinol and Fe3O4 microspheres Raman spectra were performed to represent the graphitization degree of the sample, and the results indicated that the graphitization of the sample was identical with different value of carbon contents. The thermogravimetric analysis was carried out the theoretical contents of carbon in the composite materials, and the results showed that the practical contents of carbon in the materials was lower than theoretical contents, due to autopolymerization of resorcinol and formaldehyde and generation of