fetio2uv光催化降解木质素碱溶液的研究word格式论文.docx

河北工业大学硕士论文 优秀毕业论文 万方数据 精品参考文献资料 ABSTRACT This paper proposes the integration technology of photocatalytical degradation of alkali lignin solution in corrugated plate reactor and cyclic extraction of products. The photo catalyst of Fe doping TiO2 was prepared by sol–gel method and coated on the inner surface of corrugated plate with Fe-TiO2 film. The phase transformation, crystallite size and weight percent of anatase/rutile phase ratio of Fe-TiO2 were determined by XRD and surface morphology were observed by SEM. The corrugated plate coated with Fe-TiO2 film was placed in the reactor tube with parallel orientations. During the cyclic process, the alkali lignin solution was put into the reactor and degraded by UV radiation over Fe-TiO2 catalyst, mixture of alkali lignin solution and products was transported by water pump to the extraction apparatus, and then the alkali lignin flowed to the photocatalytic reactor. The concentrated extracts were separated with silica gel column chromatography to give the pure products. 1H NMR，13C NMR spectra and GC-MS analysis were confirmed the products. The products were analyzed following an internal standard method on the gas chromatography instrument. The other extracts were analyzed with a Trace DSQ GC/MS system. At the end of the photocatalytic degradation, the lignin residue was comparatively analysis with functional groups by FT-IR. The reaction time, lignin concentration, Fe doped catalyst, catalyst film layers and folded plate angle were also investigated. Experimental results show that Fe-TiO2 catalyst with anatase structure has much higher photochemical oxidation. The main products of photocatalysis degradation of lignin were 2,6-bis(1,1-dimethylethyl)-4-methylphenol (BHT), dibutyl phthalate (DBP) and diisobutyl phthalate (DIBP). The optimum condition for lignin degradation to BHT was reaction time 5h, lignin concentration of 30g/L, the doping amount of Fe 2%, 8 layers, folding plate angle 63°, and final BHT concentrati