核壳均具有树枝状结构新型共聚物制备及应用word格式论文.docx

complexes with hydrophilic HPEI as core and hydrophobic D1-C16, D1-C8 or D2-C16 as shell. These supramolecular complexes could be used as nanocarriers to efficiently accommodate the hydrophilic anionic guests. Compared with the corresponding nanocarriers with linear shell, those with dendritic shell showed big advantages, such as higher encapsulation capacity, better resistance to the emulsion, high encapsulation capacity using a less amount of polymer and less hydrophobic chains.5.A series of novel water-soluble hyperbranched copolymers were prepared through the anionic ring-opening polymerization of glycidol using different molecular-weight HPEI as the macroinitiator. The polymerization condition and purification method were optimized. Furthermore, these novel amphiphilic hyperbranched copolymers could be used as template and stabilizer to prepare water-soluble AuNPs.KEYWORDS ： Hyperbranchedpolyethylenimine,Goldnanoparticle, Encapsulation, Supramolecualr complex, catalysis目录第一章绪论..................................................... 11.1 概述........................................................... 11.2 树枝形聚合物................................................... 21.2.1 树枝形聚合物概念............................................21.2.2 树枝形聚合物组成、结构特征及合成............................31.3 树枝形聚合物的功能化及应用 ..................................... 51.3.1 树枝形聚合物的功能化........................................51.3.2 树枝形聚合物在包裹客体分子方面的应用........................61.3.3 树枝形聚合物在分子自组装方面的应用.........................131.3.4 树枝形聚合物在膜材料中的应用...............................161.3.5 树枝形聚合物在聚合物共混中的应用...........................171.3.6 树枝形聚合物在聚电解质中的应用.............................171.3.7 树枝形聚合物在医用生物材料中的应用.........................181.3.8 树枝形聚合物在其他领域中的应用.............................191.4 树枝状共聚物的研究进展 ........................................ 19第二章新型油溶两亲性超支化共聚物的制备及客体包裹性能 ............ 252.1 引言.......................................................... 252.2 实验部分...................................................... 252.2.1