基于表面等离激元的泵浦探测及四波混频分析-pump detection and four-wave mixing analysis based on surface plasmon.docxVIP

AbstractRecently,theinvestigationofmolecularultrafastdynamicsusingfemtosecond (fs)pump-probetechniqueattractsgreatattention.Theapplication ofsurfacePlasmon polariton(SPP)andlongrangesurfacePlasmonpolariton(LRSPP)infspump-probe technologycanimprovetheaccuratenessofmolecularrelaxationdynamics,the applicationofLRSPPinfourwavemixingwillbeabletoimprovetheconversion efficiency.Inthisdissertation,fspump-probetechniquebasedonSPPandLRSPP, and fourwavemixingprocess based onLRSPPweresimulated numerically.Firstly,weinvestigatenumericallythestimulatingconditionofSPP,the conditionofSPP-basedpump-probe,andthechangeoftheconditionofstimulating theSPPandSPP-basedpump-probewithdifferentdetectingwavelengthandmetal filmthickness.Wecomparethevariationofrelativereflectivitybetweenthe SPP-basedpump-probeandstandardpump-probe.Inaddition,weanalyzethereason forthe changeusingthetwo-temperaturemodel andenergylevel transition theory.Secondly,wesimulatethestimulatingconditionofLRSPPandLRSPP-based pump-probe,andthechangeoftheconditionofstimulatingtheLRSPPand LRSPP-basedpump-probewithdifferentdetectingwavelengthandmetalfilm thickness.Alsowecomparethevariationofrelativereflectivitybetweenthe LRSPP-basepump-probe, SPP-basepump-probeand standard pump-probe.Finally,LRSPPwasusedaspumpedbeamtorealizefour-wavemixing.simulate AndWesimulatetherelationshipbetweentheinputlightwavelengthandincident angleintheLRSPP-basedfour-wavemixingprocess,aswellastherelationship betweentheangleofoutputlightandtheinputlightwavelengthwhentheexcitation wavelengthisfixed.Whentheinputlightwavelengthisdifferent,wesimulatethe relationshipbetweeninputlightwavelength,incidentangleandoutputlightangle, analyzingthevariation underthis condition.Keywords:surfacepolaritons,longrangesurfacepolaritons,pump-probe,four-wave mixing目录摘要......................................................................................................................................IABSTRACT...................................................................