基于表面等离子体增强聚合物金属杂化纳米纤维制备及传感应用-preparation and sensing application of polymer-metal hybrid nanofibers based on surface plasma enhancement.docxVIP

PreparationandSensingApplicationofPolymer/metal HybridNanofibers BasedonSurfacePlasmon EnhancementAbstractMetalnanoparticles(NPs)haveattractedextensiveattentionduetotheirdistinctive plasmonicbehaviors,whichleadtoawiderangeoflocalfieldrelatedapplications,suchas catalysis,surface-enhancedRamanscattering(SERS),fluorescenceenhancement,sensing, andphotothermaltherapy.SERS-activesubstratesandSurface-enhancedfluorescence (SEF)-activesubstratesofpolymer/metallicnanofiberswerepreparedusingasimple approachinvolvingelectrospinning.Thepolymer/metallicnanofibersareexpectedtobe highlysensitivesensorstomonitorthemetal-catalyzedchemicalreationanddetectmetal ions.Ag-AuandAg-PdbimetallicNPswerechosenastheSERSandcatalytic-active substrates.BimetallicNPsdisplayedbettersensitivityforsurface-enhancedpropertyand catalyticperformanceduetothesynergisticeffectthantheirmonometallicnanocrystals. Thesurfaceplasmonresonance(SPR)bandsofAg-AubimetallicNPsweredemonstrated tobecontinuouslytunableinawiderangeofwavelengths.Thefluorescenceenhancement washighlydependentonthespectraloverlapbetweenthesurfaceplasmonpeaksofthe Ag-AubimetallicNPsandtheexcitationwavelengthoffluorophores.Itwasstilldifficult toobtainRamanspectraofmolecules absorbedonPdresults in strongdampingofplasmon resonances ofAg orAu,whiletheAg-PdbimetallicNPs exhabitedplasmonicproperties as wellasexcellentcatalyticactivity.First,afacileapproachtoprepareelectrospunpoly(vinlyalcohol)(PVA)nanofibers withhighconcentrationofAuNPsinthefibers,hadbeendeveloped.Relativelyhigh concentrationofPVAaqueous solution(10wt%)was usedasthestabilizingagentforgold saltprecursor,aswellasthestartingsolutionforelectrospinning.SEMandTEMimages showedthatboththeamountandthesizeofAuNPswhichembeddedinPVAnanofibers,英文摘要基于表面等离子体增强的聚合物/金属杂化纳米纤维的制备及传感应用increasedwithincreasingthegoldsaltcontent,whilethegapbetweentheadjacentNPs decreased.UV-visspectraexhibitedplasmonresonancebandofisolatedsphericalAuNPs. XRDconfirmedthatthecrystalstructure ofgoldnanoparticlesinthefiberisst