合金元素对al-zn-in系阳极组织和性能影响-effect of alloying elements on microstructure and properties of al - zn - in anode.docx

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2018-05-28 发布于上海
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合金元素对al-zn-in系阳极组织和性能影响-effect of alloying elements on microstructure and properties of al - zn - in anode.docx

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合金元素对al-zn-in系阳极组织和性能影响-effect of alloying elements on microstructure and properties of al - zn - in anode

ABSTRACTSixkindsofAl,Al-Zn,Al-Zn-In,Al-Zn-In-Sn,Al-Zn-In-Sn-MgandAl-Zn-In-Sn-Mg-REanodematerialshadbeenmelted.Theelectrochemicalperformancesandthevolumesofhydrogenofsixanodeshadbeentestedinthe3%NaClsolution.Themicro-structuresofthesesixanodesandthecompositionsofsegregationshadbeeninvestigatedbytheopticalmicroscope(OM)，scanningelectronmicroscope(SEM)andenergydispersiveX-Rayfluoresencespectrometer(EDX).TheelectrochemicalbehavioursofAlalloyanodewereinvestigatedin3%sodiumchloridesolutiondynamicpotentialscanningandACimpedancemeasurements.Theexperimentsfocusedontheinfluenceofaddedelementonthemicro-structuresandmacro-electrochemicalperformancesofalloysandtheeffectofsegregationsinthealuminumanodesactivationprocess.TheresultsshowedthatthealloyappearedZn-richphasesegregationatgrainboundaryafteraddingelementZn,andhadhighertendencyofintergranularcorrosionandlowercurrentefficiency.TraceelementInreducedthegrainsizebutdendriticsegregationappearedinthealloywhichcausedthenumberofsecondphaseincreasedsignificantly.TheresultsalsoshowthatInprecipitatedwithsedimentwhichcontainedotherelementsintheformofInatoms.ThenumberofsecondphasesoaredwiththeelementSnaddedandthedendritesegregationintensified.ElementMgexistedinα-AlmatrixmainlyintheformofsolidsolutionandtherestintheformofintermetalliccompoundssuchasAl2Mg3Zn3andMgZn3whichprecipitatedinthegrains.Ifwedidnotadopteffectivemeasureswhenmeltedaluminum-magnesiumalloy,itaggravatedthereactionofaluminumandwatervaporwhichoftenaccompaniedwithmicrodefectssuchasporosityandcracking.AddedREalsoreducedthegrainsizeanditshowedthatREprecipitatedatthegrainboundariesintheformofintermetalliccompoundssuchasLaAl4,CeAl4.Thegreaterthegrainaluminumalloyanode,thelowerthecurrentefficiency,itmainlyduetocrystalgrainseparation.Themorenumberofthesecondphaseofaluminumalloyanode,thelowerthecurrentefficiency,itmainlyduetosecondphaseseparation.Thesecondphasedistributionswillalsocausethelossofefficiency.Uniformlydistributedofsecondphaseinthegrainboundarywillincreaseintergranula