机械化学法制备白云石tio2复合材料的工艺及性能分析-process and performance analysis of preparing dolomite tio _ 2 composite by mechanochemical method.docx

ABSTRACTAt present, titanium dioxide is the best white pigment in the world, and been used by many fields. However, both the serious environmental pollution during the production and the high cost of pollution_treated binging on the high price, which are important bottle-neck for its development. Producing the substitute of titanium dioxide is the most effective way to solve the problem, which is the economic way. The properties of substitute of titanium dioxide is similar to the titanium dioxide, however, the cost is too low. The substitute of titanium dioxide can replace all or most proportion of titanium dioxide, which can be extended the range of TiO2. Because of high brightness, rich resources and low price of dolomite, the composite particles of dolomite/TiO2 material is prepared by mechano-chemical method, which can replace a proportion of titanium dioxide. The dolomite/TiO2 not only reduce the serious environmental pollution in its production, but also enhance the use of dolomite.The raw materials of dolomite and titanium dioxide are mixed in this experiment by mechano-chemical method to research the technical parameters in the preparation of dolomite/TiO2 composite material. On these base, the action mechanism between dolomite and titanium dioxide is discussed lastly.The optimized technical parameters is got by the single factor experiment, the groped experiment and the orthogonal experiment, which can help to prepare the dolomite/TiO2 composite particles material. The wet grinding time of fine quartz is 3 hours; the ratio of the ball to the powder is 4:1; the slurry concentration is 60%; the dosage of dispersant is 0.5%; the grinding speed is 1200r/min. The dosage of TiO2 is 45%, which is dispersed for 1.5 hours in the water with 60% slurry concentration and 0.5% dispersant. At the reaction stage, the grinding speed is 1100r/min, the ratio of the ball to the powder is 4:1, the reaction time is 90 minutes. The whiteness of the composite particles material p