激光表面改性对双酚a型聚碳酸酯材料表面性能影响-effect of lase surface modification on surface properties of bisphenol a polycarbonate material.docx

下载文档 降价啦

6
0
约4.78万字
约 70页
2018-05-28 发布于上海
举报
版权申诉
保障服务

激光表面改性对双酚a型聚碳酸酯材料表面性能影响-effect of lase surface modification on surface properties of bisphenol a polycarbonate material.docx

1、本文档共70页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。

激光表面改性对双酚a型聚碳酸酯材料表面性能影响-effect of lase surface modification on surface properties of bisphenol a polycarbonate material

AbstractThermoplasticpolymermaterialpolycarbonate(PC)hasbeenusedasaveryimportantengineeringplasticbecauseofitsmanyexcellentproperties.However,duetoitslowsurfaceenergyandhighchemicalstability,ithasapoorsurfaceadsorbabilityandadhesivenesstootherfilmsandcoatings.Thisgreatlylimitsitsdirectapplicationsinsomefields.Therefore,itisnecessarytomodifythePCsurfaceandtoimproveitssurfaceproperties.Inthiswork,355nm-wavelengthultraviolet(UV)nanosecondpulselasermodificationonthesurfaceofbisphenolApolycarbonate(PC)coatedwithafilmofwaterwassuggested,andtheeffectoflaserprocessingparametersonPCsurfacepropertieswasexplored.Itshowedthatlaserfluenceandpulsefrequencywerethetwomoreimportantparameters.Throughanalysesandmeasurementsofscanningelectronicmicroscopy,X-rayphotoelectronspectroscopy,etc.,thechangeofthesurfacemicrostructure,roughness,watercontactangle,wettability,chemicalcomposition,andsurfaceenergybeforeandafterlasermodificationwasinvestigated.ItindicatedthatthereexistedacertainUVlaserfluencethresholdFth,whichwascorrespondingtoacertainlaserpulsefrequency,respectively.WhenthelaserfluencesappliedwerelessthanFth,thewatercontactanglehadadecreasingtendency,thehydrophilicitywasslightlyimproved,therelativecontentofoxygen-containingpolargroups(e.g.,O-CandC=O)increased,themicrostructureandroughnessonlyhadaveryslightchange,andthewettingbehaviorcompliedwiththeWenzellaw.Ontheotherhand,whenthelaserfluencesappliedwerelargerthanFth,theporousmicrostructurewithperiodicalV-typegroovegenerated,andtheroughnesshadasignificantincrease.Here,thesurfacewashydrophobic,andthewettingbehaviorcouldbeexplainedbytheCassiemodel.Next,accordingtothevanOssacid–basetheory,thesurfaceenergywascalculatedbymeasuringthecontactangleofthreeliquidswater,ethyleneglycolandmethyleneiodideonthemodifiedsurface.ItwasfoundthatthesurfaceenergyofthemodifiedPCsurfacehadasignificantincrease.Thiswouldbeveryhelpfultoimprovetheadsorbabilityandadhesiveness.Theadsorbabilitytometal(complex)ionsonthemodifiedPCsurfacewasalsostudied.Itshowedthatth