接枝丙烯胺共聚物的支链结构与其性能的关系分析-analysis of the relationship between branched chain structure and properties of grafted acrylamide copolymer.docxVIP

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接枝丙烯胺共聚物的支链结构与其性能的关系分析-analysis of the relationship between branched chain structure and properties of grafted acrylamide copolymer.docx

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接枝丙烯胺共聚物的支链结构与其性能的关系分析-analysis of the relationship between branched chain structure and properties of grafted acrylamide copolymer

Study on Relation between Branched Chain Structure and Properties of Grafted Acrylamide-Based CopolymersIntroduction of the author: Jiang Liufeng, male, was born in March, 1983, whose tutor was Professor Zhong Chuangrong. He graduated from Chengdu University of Technology in chemical technology major and was granted the Master Degree in June, 2010.AbstractThree novel surfactant macromonomers: p–vinylbenzyl-terminated octylphenoxy poly(ethylene oxide) (VEn, polymerization number (n): 4, 18, 24) were synthesized. Three kinds of grafted copolymers were synthesized by an aqueous free radical copolymerization technique using acrylamide (AM), (VEn, n: 4, 18, 24), and sodium 2-acrylamido-2-methyl propane sulphonate (NaAMPS), respectively. The influence ofreaction conditions on viseosifieation performance of the polymer solutions was studied, and the suitable reaction parameters of PAAEn (n: 4, 18, 24) were obtained, respectively. The three macromonomers and their copolymers were characterized by Fourier transform infrared (FT-IR) spectroscopy and proton nuclear magnetic resonance (1H-NMR). Influence of branched chain length on solution performances, viscoelastic properties, and associating microstructure in solutions were investigated for the copolymers. Compared with partially hydrolyzed polyacrylamide (HPAM) with superhigh molecular weights, the molecular weights of the three kinds ofcopolymers were low. The copolymers exhibited the hydrophobic association behavior in water and brine solution, and good solution properties such as solubility, thickening properties, heat resistance, salt resistance, shear resistance, viscoelastic properties, and surfactant and interfacial activities. The critical associated concentrations were 0.10 g/dL for PAAEn. The PAAE4 polymers with the shortest branched chain length displayed the best solution performance. The benzyl-capped octylphenoxy poly(ethylene oxide) (PEO) side chain could not only increase the rigidity of polymer