介孔材料的模板合成及其应用分析-template synthesis and application analysis of mesoporous materials.docxVIP

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介孔材料的模板合成及其应用分析-template synthesis and application analysis of mesoporous materials.docx

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介孔材料的模板合成及其应用分析-template synthesis and application analysis of mesoporous materials

ABSTRACTMesoporous materials have regularly periodic pore structures, highly uniform and relatively large pore size (2-50 nm), large pore volume, high surface area and adjustable ordered stuctures. These prominent performances give the mesoporous materials tremendous applications in catalysis, adsorption and separation, biopharmaceutical synthesis, material assembly. In this paper, template methods were used to synthesize mesoporous carbon and mesoporous alumina, and furthermore, the adsorption performance of mesoporous alumina in the removal of heavy metal ions in water was studied.For the synthesis of mesoporous carbon, the resin prepared by phenol and formaldehyde as precursor, F127 and P123 triblock copolymer as template agents, the highly orderd and stable mesoporous carbon was synthesized using soft template method. The experiments emphasize on the influences of the template type, the amount of the template agent, calcination temperature and thermal polymerization time on the pore size, volume and surface area. The results show that ordered mesopores carbon could be obtained using the two kinds of surfactants and the amount of the template agent would change the mesostructure from hexagonal pore to cubic pore. The synthesis of ordered mesoporous carbon will lay the basis for the future work of biodiesel preparation catalyzed by a novel mesoporous carbon-based solid acid catalyst.For the synthesis of mesoporous alumina, the effects of different synthesis methods, the types and amounts of template agents, calcination temperature on mesostructure and pore parameters were mainly investigated. The results suggest that using the sol-gel method, mesoporous alumina with worm-like channels could be synthesized with Triton X-100 surfactant as the template; meanwhile, using ethanol evaporation-induced self-assembly (EISA) method, highly orderly mesoporous alumina could be achieved with PEO-PPO-PEO triblock copolymer as template. Moreover, the functions of gel systems su