金、银纳米粒子合成以及表面光谱特征和应用-synthesis, surface spectral characteristics and applications of gold and silver nanoparticles.docx

The Characteristics and Applications of Functionalized Molecules Surface Spectrum on Metal NanoparticlesAbstractNanosized particles of metals, particularly silver and gold, have recently received increasing attention, due to their size, shape and environmental tunable optical and electrical properties. They have shown various potential applications in many fields, including nanodevices, nanocatalysis, biosensors and chemical sensors. For those applications, it is necessary to immobilize metal particles onto a solid substrate. Therefore, efforts have devoted to the assembly of nanoparticles in high ordered structures. Among various methods that used for the assembly of metal nanoparticles, self-assembly technique is one of the most flexible approaches for the immobilization of metal particles on substrates. In addition, due to the small size effect, macroscopic quantum tunneling effect, dielectric confinement effect, the metal nanoparticles has some special physical properties. Especially the metal nanoparticles having a good optical characteristics because of the surface plasmon. In the last few years, as further confirmation of the gold, silver and other metal nanoparticles surface-enhanced Raman scattering effect for nanoparticle optical properties ,the gold, silver and other metals has become a hot topic of nano-materials research field. One of the most important properties of the metal nanoparticls in the nanodevices is the charge transfer at the interface between the metal nanoparticls and absorbed functionalized molecules. The effect of the substrates on the interfacial charge transfer of the assembled metal nanoparticls, however, has scarcely been studied. It has been well known that the charge transfe at the molecules/metal interface has contributions to the Surface-enhanced Raman scattering (SERS) of the molecules absorbed on the metal nanoparticles. Besides providing the spectral information associated the interfacial charge transfer, the SERS spectroscopy