金属离子改性吸附剂的制备及其对焦化苯中唾吩的脱除分析-preparation of metal ion modified adsorbent and analysis of its removal of salivary benzene from coking benzene.docxVIP
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金属离子改性吸附剂的制备及其对焦化苯中唾吩的脱除分析-preparation of metal ion modified adsorbent and analysis of its removal of salivary benzene from coking benzene
附,但是粒径太小会增大床层间的传质阻力,增大能耗。溶液流速在0.2mL/min时较好,流速太大或太小都会使穿透时间变短。吸附反应在室温下进行即可,高温可能会减弱吸附剂与唾盼之间的作用力,从而使吸附性能降低。吸附法更适用于低浓度喔吩的脱除,当曝吩浓度为200mgIL时,吸附剂的硫容为4.18mg/g,处理量为20.91mL倍。关键词:焦化苯,睡盼,脱硫,吸附,y-Ah03分子筛111PREPARATIONOFSORBENTSMODIFIEDBYMETALLICIONANDTHEIRPERFORMANCEOFREMOVn斗GTHIOPHENEINCOKlNGBENZENEABSTRACTBenzeneisanimportantchernicalrawmaterialandcomesmainlyfrompe盯oleumandcokingindus盯.Alongwiththerapiddevelopmentofchernicalindustryinrecentyears,styrene,phenolandotherdownstreamproductsexpandgradually,resultingincontinuedgrowthofthedemandforpurebenzene.Current1y,theoilresourcesbecomemoreandmorescarce,whilethecoalresourcesisrelativelyrichinChina.Theabundantcokingbenzeneisgeneratedwiththerapiddevelopmentofcokingindustry.Buttheexistenceofthiophenicsulfidesincokingbenzene,whichcancorrodemetalequipment,poisoncatalystsduringthefollowingapplication,causeenvironmentalpollution,andsoon.Thiswillseriouslylimititsutilizationrange.Sothenationalstandardofthesulfurcontentincokingbenzenebecomesmoreandmorerigid.Adsorptionremovalofthiophenicsulfideshasdevelopedinrecentyearsasadesul臼rizationmethod,whichhastheadvantagesofrnilderreactionconditions,smallerequipmentcorrosion,loweroperatingcosts,recyclabilityofthiophene,)essenviroomentalpollution,andso00.Fromthepointofenergysavingandful1utilizationofreSQurces,thismethodisverypromising.However,Vandsoon.Sotheresearchanddevelopmentofhighlyefficientsorbentsisthekeytoachieveindustrialapplicationsofthismethod.Sorbentofy-A}z03modifiedbysupportingmetalliciony-Ah03isagoodsorbentcarrier,withthefeatursofhighsurfacearea,goodthennalstability,simplestructure,lowexpense,easyacquirement,andsoon.Itwasselectedas由esorbentcarrierandwasmodifiedbyincipient-wetnessimpregnationmethodinthedifferentmetallicnitratesolution.Accordingtheadsorptionbehaviorinthiophene-benzenesolution,itisfoundthatthesorbentmodifiedinsilvernitratesolutionhasthebestdesulfurizationability.Theamountofactivecomponentloadedony-Ah03canbeaccuratelycontrolledbyincipient-wetnessirnpre伊ationmethod,butthereisth
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