金属载体催化剂催化co气相偶联合成草酸二甲酯的分析-analysis of catalytic co gas-phase coupling to dimethyl oxalate by metal-supported catalyst.docxVIP

目录第一章文献综述..........................................................................................................11.1课题背景及意义........................................................................................11.2草酸二甲酯................................................................................................21.2.1草酸二甲酯的性质和用途.............................................................21.2.2草酸二甲酯合成方法概述.............................................................21.2.3CO气相催化偶联合成DMO31.3金属载体规整结构催化剂及反应器........................................................71.3.1规整结构催化剂的研究进展.........................................................81.3.2规整结构催化剂的类型和特点.....................................................91.3.3金属载体规整结构催化剂的制备...............................................101.4论文的选题和研究内容..........................................................................12第二章实验部分........................................................................................................142.1实验原料及仪器......................................................................................142.2实验原理..................................................................................................152.2.1亚硝酸甲酯的生成.......................................................................152.2.2草酸二甲酯的生成.......................................................................152.3催化剂的制备..........................................................................................162.3.1金属载体的表面处理...................................................................162.3.2氧化铝浆料及溶胶的制备...........................................................162.3.3氧化铝涂层的制备.......................................................................162.3.4活性组分的负载...........................................................................172.4催化剂的评价..........................................................................................172.4.1亚硝酸甲酯的发生装置...............................................................172.4.2一氧化碳偶联合成草酸二甲酯反