壳聚糖基复合材料制备及铜离子吸附分析-preparation of chitosan-based composites and analysis of copper ion adsorption.docxVIP

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壳聚糖基复合材料制备及铜离子吸附分析-preparation of chitosan-based composites and analysis of copper ion adsorption.docx

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壳聚糖基复合材料制备及铜离子吸附分析-preparation of chitosan-based composites and analysis of copper ion adsorption

Environmentalpollutioncausedbyheavymetalioninindustrialwastewaterhasarousedmoreandmorepeople′sattention.Chitosananditsderivativeshavewidelybeenusedinwatertreatmentduetoabundantresources,environmental-friendlycharacterandefficientadsorptioncapacity.Inthispaper,usingchitosanasthesubstrate,avarietyofmethodswereadoptedtoimproveitsstrengthandcopperionsadsorptionproperties.Thecrosslinkedchitosan(CCTS),polyacrylamide/chitosan(PAM/CTS),chitosan/ZSMmolecularsieve(CTS/ZSM)andchitosan/Ymolecularsieve(CTS/Y)compositewerepreparedundermicrowaveradiation.ThesecompositeswerecharacterizedwithFTIR,TGA,XRDandSuperfielddepth3-Dmicroscopy.Theadsorptionpropertiesofcopperionsontothesesamplesweredetailedstudied.ItwasshowedthatcomparedwithCCTS,thePAM/CTS,CTS/ZSM,CTS/YhadmoregreatCu(Ⅱ)adsorptioncapacity.TheadsorptioncapacityofCu(Ⅱ)ontoCCTS,PAM/CTS,CTS/ZSMandCTS/Ydecreasedwiththeincreaseoftheamountofcrosslinkingagent.WhentheratioofPAM/CTSwas0.3/0.5,theadsorptioncapacityofCu(Ⅱ)ontoPAM/CTSreachedthemaximum.WhenthecontentofYmolecularsievewas6%andthecontentofZSMmolecularsieveswas4%,CTS/YandCTS/ZSMhadthemaximumadsorptioncapacity.Itwasshownfromkineticstudiesthatthepseudo-secondorderkineticequationwaswellfittedtocopperionadsorptiontoCCTSandPAM/CTS.Otherwisethepseudo-secondordermodelcouldnotexplaintheadsorptionofCu(II)ontoCTS/YandCTS/ZSMcomposites.ForthewholeadsorptionprocessofCCTS,PAM/CTS,CTS/Y,CTS/ZSM,theintra-particlediffusionmodelwasthemainlimitingstep.ThermodynamicstudyshowedthattheLangmuirisothermmodelgavebetterfitstocopperionsadsorptionontoCTS,CCTS,PAM/CTS,CTS/YandCTS/ZSM.TheadsorptionofCopperionsonthesesampleswasallfavorable.DuetointroductionofcrosslinkingstructureandZSMmolecularsieve,chitosanmatrixhadweakeningabilityofcrystallizationandlowcrystallizationdegree.AndthethermalstabilityofCTSwasimproved.CTS/ZSMcompositehadcertainreusability.Polyurethane/chitosanresin(PU/CTS)andchitosan/methylcellulose/bentonitecompositemicrospheres(CTS/MC/BC)werepreparedusingsimpleprocess.Theadsorptionpropertieso